Measurements of C3H+3, C5H+3, C6H+6, C7H+5, and C10H+8 dissociative recombination rate coefficients

1993 ◽  
Vol 99 (1) ◽  
pp. 237-243 ◽  
Author(s):  
H. Abouelaziz ◽  
J. C. Gomet ◽  
D. Pasquerault ◽  
B. R. Rowe ◽  
J. B. A. Mitchell



2020 ◽  
Author(s):  
Joshua Dreyer ◽  
Erik Vigren ◽  
Michiko Morooka ◽  
Jan-Erik Wahlund ◽  
Stephan Buchert ◽  
...  

<p>The present study combines RPWS/LP and INMS data from Cassini's orbit 292, which reached an altitude of 1685 km at the lowest point, to constrain the effective recombination coefficient α<sub>300</sub> from measured densities and electron temperatures at a reference electron temperature of 300 K. Assuming photochemical equilibrium at these low altitudes and linking established methods to calculate the electron production rate and the dissociative recombination rate results in a formula to calculate an upper limit for α<sub>300</sub>. This is then compared against rate constants of individual recombination reactions as measured in the laboratory.<br>We derive upper limits for α<sub>300</sub> of ∼ 2.5∗10<sup>-7</sup>cm<sup>3 </sup>s<sup>-1</sup>, which suggest that Saturn's ionospheric positive ions are dominated by species with low recombination rate coefficients. An ionosphere dominated by water group ions or complex hydrocarbons, as previously suggested, is incompatible with this result, as these species have recombination rate constants > 5∗10<sup>-7 </sup>cm<sup>3 </sup>s<sup>-1</sup> at an electron temperature of 300 K. The results do not give constraints on the nature of the negative ions.</p>





2004 ◽  
Vol 33 (2) ◽  
pp. 216-220 ◽  
Author(s):  
C.H. Sheehan ◽  
J.-P. St.-Maurice


2009 ◽  
Vol 42 (10) ◽  
pp. 105203 ◽  
Author(s):  
Fan-Chang Meng ◽  
Li Zhou ◽  
Min Huang ◽  
Chong-Yang Chen ◽  
Yan-Sen Wang ◽  
...  




1992 ◽  
Vol 97 (2) ◽  
pp. 1028-1037 ◽  
Author(s):  
A. Canosa ◽  
J. C. Gomet ◽  
B. R. Rowe ◽  
J. B. A. Mitchell ◽  
J. L. Queffelec


2005 ◽  
Vol 437 (3) ◽  
pp. 1151-1157 ◽  
Author(s):  
S. Böhm ◽  
A. Müller ◽  
S. Schippers ◽  
W. Shi ◽  
M. Fogle ◽  
...  


Science ◽  
2019 ◽  
Vol 365 (6454) ◽  
pp. 676-679 ◽  
Author(s):  
Oldřich Novotný ◽  
Patrick Wilhelm ◽  
Daniel Paul ◽  
Ábel Kálosi ◽  
Sunny Saurabh ◽  
...  

The epoch of first star formation in the early Universe was dominated by simple atomic and molecular species consisting mainly of two elements: hydrogen and helium. Gaining insight into this constitutive era requires a thorough understanding of molecular reactivity under primordial conditions. We used a cryogenic ion storage ring combined with a merged electron beam to measure state-specific rate coefficients of dissociative recombination, a process by which electrons destroy molecular ions. We found a pronounced decrease of the electron recombination rates for the lowest rotational states of the helium hydride ion (HeH+), compared with previous measurements at room temperature. The reduced destruction of cold HeH+ translates into an enhanced abundance of this primordial molecule at redshifts of first star and galaxy formation.



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