scholarly journals Rare events and first passage time statistics from the energy landscape

2020 ◽  
Vol 153 (13) ◽  
pp. 134115
Author(s):  
Thomas D. Swinburne ◽  
Deepti Kannan ◽  
Daniel J. Sharpe ◽  
David J. Wales
2020 ◽  
Vol 2020 (10) ◽  
Author(s):  
Ran Li ◽  
Kun Zhang ◽  
Jin Wang

Abstract We explore the thermodynamics and the underlying kinetics of the van der Waals type phase transition of Reissner-Nordström anti-de Sitter (RNAdS) black holes based on the free energy landscape. We show that the thermodynamic stabilities of the three branches of the RNAdS black holes are determined by the underlying free energy landscape topography. We suggest that the large (small) RNAdS black hole can have the probability to switch to the small (large) black hole due to the thermal fluctuation. Such a state switching process under the thermal fluctuation is taken as a stochastic process and the associated kinetics can be described by the probabilistic Fokker-Planck equation. We obtained the time dependent solutions for the probabilistic evolution by numerically solving Fokker-Planck equation with the reflecting boundary conditions. We also investigated the first passage process which describes how fast a system undergoes a stochastic process for the first time. The distributions of the first passage time switching from small (large) to large (small) black hole and the corresponding mean first passage time as well as its fluctuations at different temperatures are studied in detail. We conclude that the mean first passage time and its fluctuations are related to the free energy landscape topography through barrier heights and temperatures.


1980 ◽  
Vol 45 (3) ◽  
pp. 777-782 ◽  
Author(s):  
Milan Šolc

The establishment of chemical equilibrium in a system with a reversible first order reaction is characterized in terms of the distribution of first passage times for the state of exact chemical equilibrium. The mean first passage time of this state is a linear function of the logarithm of the total number of particles in the system. The equilibrium fluctuations of composition in the system are characterized by the distribution of the recurrence times for the state of exact chemical equilibrium. The mean recurrence time is inversely proportional to the square root of the total number of particles in the system.


Author(s):  
Natalie Packham ◽  
Lutz Schloegl ◽  
Wolfgang M. Schmidt

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