Effect of Holding Time on Populations of Microparticles in Spheroidal Graphite Irons

Non-metallic microparticles in spheroidal graphite irons are a product of the inoculation and the Mg-treatment of the liquid melt. Besides the influence on the mechanical properties of these iron–carbon–silicon alloys, they are also responsible for the nucleation and the morphology of the graphite phase. The present investigation is undertaken to study holding time effects of a (Ba, Ca, Al)–ferrosilicon (called Ba-inoculant) and (Ca, Al)–ferrosilicon (called Ca-inoculant) inoculants on the overall distribution of microparticles. Using the 2D to 3D conversions method, which is typically used for graphite nodules, the non-metallic microparticles’ statistical parameters, such as size distributions and number densities, are quantified. The total number of particles is similar after Mg-treatment and inoculation for Ca-inoculant but not for Ba-inoculated samples, which lose approximately 25 pct of microparticles after 1 minute of holding time. Iron treated with the Ca-inoculant loses about 37 pct of its nodules after 5 minutes, while the Ba-inoculated melts maintain their performance even after 10 minutes. Based on extrapolating the trend of the undercooling, Ba-inoculated samples would reach the uninoculated undercooling values in 48 minutes, while Ca-inoculated samples in only 11 minutes. By evaluating the size distributions of the non-metallic microparticles, the Ostwald ripening hypothesis or particle aggregation can be verified. The results suggest that sulfides are more critical for graphite nucleation since they can be correlated with the graphite number densities. However, due to the small difference in the microparticle population of the uninoculated sample with Ca-inoculated samples, other aspects of the fading mechanism need to be considered, such as transient metastable states, since the central hypothesis of loss of inclusions cannot alone explain the decrease in the nucleation frequency of graphite.

Plastic After an Extreme Storm: The Typhoon-Induced Response of Micro- and Mesoplastics in Coastal Waters

Extreme storms, such as tropical cyclones, are responsible for a significant portion of the plastic debris transported from land to sea yet little is known about the storm response of microplastics and other debris in offshore and open waters. To investigate this, we conducted floating plastic surveys in the center of Sagami Bay, Japan approximately 30 km from the coastline, before and after the passage of a typhoon. The concentrations (number of particles/km2) of micro- and mesoplastics were two orders of magnitude higher 1-day after the typhoon than the values recorded pre-typhoon and the mass (g/km2) of plastic particles (sum of micro- and mesoplastics) increased 1,300 times immediately after the storm. However, the remarkably high abundance of micro- and mesoplastics found at 1-day after the typhoon returned to the pre-typhoon levels in just 2 days. Model simulations also suggested that during an extreme storm a significant amount of micro- and mesoplastics can be rapidly swept away from coastal to open waters over a short period of time. To better estimate the annual load of plastics from land to sea it is important to consider the increase in leakages of plastic debris into the ocean associated with extreme storm events.

Dynamical Spectra in Two-Dimensional Dusty Plasmas

Equilibrium molecular dynamics (EMD) simulation has been employed to explore the dynamical structure factors (DSFs) of two-dimensional (2D) dusty plasma systems for a wide domain of plasma parameters of Coulomb coupling (Γ) and Debye screening strength (κ). The influence of varying wave vectors (k) on plasma DSFs S (k, ω) have been reported with different combinations of plasma state points (Γ, κ). New simulations have been tested for the influence of different wave vectors on plasma density S (k, ω) in addition to different combinations of plasma state points. New results of plasma density S (k, ω) show that amplitude of oscillation and frequency will vary with increasing value of Coulomb coupling parameter (Γ) and Debye screening strength (κ). These simulation techniques show that transient behavior has been reported for frequency (ω) with various values of Debye screening strength (κ) and number of particles (N). Moreover, EMD simulation has been checked in order to investigate the behavior of plasma DSFs with increasing number of particles (N). The outcomes of EMD simulations are matched to earlier known numerical and experimental data. It has been shown that fluctuation of dynamical density increases at intermediate to higher values of coupling parameter. However, it shows less fluctuation at higher values of Debye screening strength (κ).

Exploring Reggeon bound states in strongly-coupled $$ \mathcal{N} $$ = 4 super Yang-Mills

The multi-Regge limit of scattering amplitudes in strongly-coupled $$ \mathcal{N} $$ N = 4 super Yang-Mills is described by the large mass limit of a set of thermodynamic Bethe ansatz (TBA) equations. A non-trivial remainder function arises in this setup in certain kinematical regions due to excitations of the TBA equations which appear during the analytic continuation into these kinematical regions. So far, these analytic continuations were carried out on a case-by-case basis for the six- and seven-gluon remainder function. In this note, we show that the set of possible excitations appearing in any analytic continuation in the multi-Regge limit for any number of particles is rather constrained. In particular, we show that the BFKL eigenvalue of any possible Reggeon bound state is a multiple of the two-Reggeon BFKL eigenvalue appearing in the six-gluon case.

Large deviations for a binary collision model: energy evaporation

<abstract><p>We analyze the large deviations for a discrete energy Kac-like walk. In particular, we exhibit a path, with probability exponentially small in the number of particles, that looses energy.</p></abstract>

Approximating quasi-stationary distributions with interacting reinforced random walks

We propose two numerical schemes for approximating quasi-stationary distributions (QSD) of finite state Markov chains with absorbing states. Both schemes are described in terms of interacting chains where the interaction is given in terms of the total time occupation measure of all particles in the system and has the impact of reinforcing transitions, in an appropriate fashion, to states where the collection of particles has spent more time. The schemes can be viewed as combining the key features of the two basic simulation-based methods for approximating QSD originating from the works of Fleming and Viot (1979) and Aldous, Flannery and Palacios (1998), respectively. The key difference between the two schemes studied here is that in the first method one starts with $a(n)$ particles at time $0$ and number of particles stays constant over time whereas in the second method we start with one particle and at most one particle is added at each time instant in such a manner that there are $a(n)$ particles at time $n$. We prove almost sure convergence to the unique QSD and establish Central Limit Theorems for the two schemes under the key assumption that $a(n)=o(n)$. Exploratory numerical results are presented to illustrate the performance.

Evaluation of Pollen Adhesion to Verofilcon-A Soft Contact Lenses

Purpose: A new 1-day disposable soft contact lens (SCL), verofilcon-A, constructed of silicone hydrogel material, has recently become available in Japan. This SCL has a very smooth surface produced by using the SMARTSURFACE ® Technology, and it was expected that pollen particles and protein components would not adhere easily to its surface. We examined the degree of pollen adhesion to the surface of the verofilcon-A material SCL and compared the results with those of other 1-day disposable SCLs (1DSCL). Methods: To determine the number of pollen grains attached to the surface of different types of SCLs, 0.01 mg/ml of cedar pollen solution was dropped onto the surface of 13 types of 1DSCL. After 24 h, each 1DSCL was rinsed in a shaker and washed five times with saline (n = 10 for each 1DSCL type). The number of pollen particles adhered to the 1DSCL and the percentage of surface area occupied by pollen was determined. Results: The number of pollen particles on the 1DSCLs ranged from 0 to 185 in the 200 × 200 µm area. The number of particles was lowest in the delefilcon-A and verofilcon-A SCLs with 0 particles, and the number was higher in the other 11 1DSCLs. The number of pollen particles was negatively correlated with the water content (r = −0.48), oxygen permeability (Dk; r = −0.43), oxygen transmissibility (r = −0.42), and center thickness (r = −0.33) of the 1DSCLs. The pollen adhesion area ranged from 0.0% to 3.1% and was lowest in the delefilcon-A and verofilcon-A 1DSCLs. There were significant differences in the pollen adhesion area between colored 1DSCLs (2.73 ± 1.97%) and clear 1DSCLs (1.03 ± 1.01%, P<0.001) and between hydroxyethyl methacrylate-based 1DSCLs (1.84 ± 1.45%) and silicone hydrogel-based 1DSCLs (0.05 ± 0.16%, P<0.001). Conclusion: These findings indicate that the verofilcon-A 1DSCL processed with SMARTSURFACE™ Technology is an excellent option for SCL users with allergic conjunctivitis during the high pollen season.

Convergence of a particle approximation for the quasi-stationary distribution of a diffusion process: uniform estimates in a compact soft case. p, li { white-space: pre-wrap; }

We establish the convergences (with respect to the simulation time $t$; the number of particles $N$; the timestep $\gamma$) of a Moran/Fleming-Viot type particle scheme toward the quasi-stationary distribution of a diffusion on the $d$-dimensional torus, killed at a smooth rate. In these conditions, quantitative bounds are obtained that, for each parameter ($t\rightarrow \infty$, $N\rightarrow \infty$ or $\gamma\rightarrow 0$) are independent from the two others. p, li { white-space: pre-wrap; }

Effects of an acute exercise bout in hypoxia on extracellular vesicle release in healthy and prediabetic subjects

Purpose: To investigate exosome-like vesicle (ELV) plasma concentrations and markers of multivesicular body (MVB) biogenesis in skeletal muscle in response to acute exercise. Methods: Seventeen healthy (BMI: 23.5±0.5kg·m-2) and fifteen prediabetic (BMI: 27.3±1.2kg·m-2) men were randomly assigned to two groups performing an acute cycling bout in normoxia or hypoxia (FiO2 14.0%). Venous blood samples were taken before (T0), during (T30) and after (T60) exercise and biopsies from m. vastus lateralis were collected before and after exercise. Plasma ELVs were isolated by size exclusion chromatography, counted by nanoparticle tracking analysis (NTA), and characterized according to international standards, followed by expression analyses of canonical ELV markers in skeletal muscle. Results: In the healthy normoxic group, the total number of particles in the plasma increased during exercise from T0 to T30 (+313%) followed by a decrease from T30 to T60 (-53%). In the same group, an increase in TSG101, CD81 and HSP60 protein expression was measured after exercise in plasma ELVs; however, in the prediabetic group, the total number of particles in the plasma was not affected by exercise. The mRNA content of TSG101, ALIX and CD9 were upregulated in skeletal muscle after exercise in normoxia; whereas, CD9 and CD81 were downregulated in hypoxia. Conclusions: ELV plasma abundance increased in response to acute aerobic exercise in healthy subjects in normoxia, but not in prediabetic subjects, nor in hypoxia. Skeletal muscle analyses suggested that this tissue did not likely play a major role of the exercise-induced increase in circulating ELVs.

Lieb–Robinson bounds and growth of correlations in Bose mixtures

For a mixture of interacting Bose gases initially prepared in a regime of condensation (uncorrelation), it is proved that in the course of the time evolution observables of disjoint sets of particles of each species have correlation functions that remain asymptotically small in the total number of particles and display a controlled growth in time. This is obtained by means of ad hoc estimates of Lieb–Robinson type on the propagation of the interaction, established here for the multi-component Bose mixture.