Ceramic materials based on zirconium dioxide for the production of solid oxide fuel cells

2020 ◽  
Author(s):  
Elmira I. Denisova ◽  
Anna V. Rozhdestvenskaya ◽  
Eugene M. Belousov ◽  
Vadim V. Kartashov ◽  
Alexey I. Vylkov
Author(s):  
S. Shakrawar ◽  
J. G. Pharoah ◽  
B. A. Peppley ◽  
S. B. Beale

Solid oxide fuel cells represent a potentially important application for ceramic materials. There are, however, some significant issues which can affect the reliability and durability of the cell. The generation of stresses and associated strains in fuel cells is an important concern that needs to be addressed in order to avoid mechanical failure of the cell. Few comprehensive studies have been published on the subject of stress analysis of planar and tubular SOFCs to-date, although various numerical methodologies have been used to obtaining the stress distribution in specific SOFC components over the last 10 years. The objective of this paper is to summarize the state-of-the art of solid oxide fuel cell stress analysis efforts so that the salient issues can be identified.


2014 ◽  
Vol 51 (4) ◽  
pp. 231-242
Author(s):  
Beom-Kyeong Park ◽  
Rak-Hyun Song ◽  
Seung-Bok Lee ◽  
Tak-Hyoung Lim ◽  
Seok-Joo Park ◽  
...  

2021 ◽  
Author(s):  
Alexey Platenkin ◽  
Vladimir Chernyshov ◽  
Tatyana Chernyshova ◽  
Maxim Dutov

2019 ◽  
Vol 58 (5) ◽  
pp. 105-109
Author(s):  
Yulia A. Mityushova ◽  
◽  
Sergey A. Krasikov ◽  
Alexey A. Markov ◽  
Elmira I. Denisova ◽  
...  

The creation of solid oxide fuel cells (SOFC) is one of the promising solutions to the problem of electricity supply. It is advantageous to use stabilized zirconium dioxide (ZrO2) as solid electrolytes in SOFC. In this paper, zirconium dioxide powders with additives of yttrium and scandium oxides (ZrO2–Y2O3, ZrO2–Sc2O3 and ZrO2–Y2O3–Sc2O3) were synthesized. Ceramic samples were obtained from the powders to study the effect of stabilizing additives on the conductive properties of zirconium dioxide. The addition of yttrium oxide Y2O3 in an amount of 8 mol. % contributed to the formation of a solid cubic solution of zirconium dioxide, and scandium oxide Sc2O3 increased the strength and conductive characteristics of the material. The definition of the conductive characteristics was carried out by impedance spectroscopy. Platinum paste was preliminarily applied by printing, which, when measured, ensured contact with the entire surface of the sample under study. It is shown that the addition of yttrium oxide contributes to the formation of a solid cubic solution of zirconium dioxide, and scandium oxide increases the strength (microhardness) and conductive characteristics of the material. Of interest is the simultaneous alloying of zirconium dioxide with scandium and yttrium oxides. The results of determining the properties of ceramic samples showed that the increase in electrical conductivity is more influenced by the addition of Sc2O3 compared with the addition of Y2O3. Stabilization without yttrium oxide leads to unstable conductivity values over time. A sample of ZrO2 – 1 mol%. – Y2O3 – 8 % mol. Sc2O3 has the potential to be used as an electrolyte in solid oxide fuel cells.


2005 ◽  
Vol 242-244 ◽  
pp. 129-142 ◽  
Author(s):  
Teruhisa Horita ◽  
Haruo Kishimoto ◽  
Katsuhiko Yamaji ◽  
Natsuko Sakai ◽  
Yue Ping Xiong ◽  
...  

Oxygen diffusion was measured at oxygen/cathode/electrolyte interfaces and at oxide scales/alloy interconnects in Solid Oxide Fuel Cells (SOFCs). A stable isotope oxygen exchange technique (16O/18O exchange) was adopted to label the diffusion profiles in the oxides, and secondary ion mass spectrometry (SIMS) depth profiles were examined to determine the diffusion coefficients in the oxide ceramic materials. Diffusivity of oxygen in LaMnO3 cathode was measured under polarized condition (that is, considering the electrochemical process and diffusion). Also, oxygen diffusion in the oxide scales formed on the alloy was measured to clarify the formation mechanism of oxide scale.


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