Speciation of Chlorometallate Ionic Liquids Based on Gallium(III) and Indium(III)

A range of ionic liquids was prepared by mixing 1-alkyl-3-methylimidazolium chloride with gallium(iii) chloride or indium(iii) chloride in various ratios, producing both acidic and basic compositions. Their speciation was investigated using 71Ga NMR or 115In NMR spectroscopy, as well as extended X-ray absorption fine structure. Polynuclear Lewis acidic anions, [MxCl3x+1]–, were found in chlorogallate(iii) ionic liquids, but not in chloroindate(iii) systems.

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Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2

Dalton Transactions ◽

10.1039/c7dt01019b ◽

2017 ◽

Vol 46 (22) ◽

pp. 7223-7231 ◽

Cited By ~ 5

Author(s):

John B. Brazier ◽

Mark A. Newton ◽

Elena M. Barreiro ◽

Luis A. Adrio ◽

Leticia Naya ◽

...

Keyword(s):

Mass Spectrometry ◽

Catalytic Activity ◽

Fine Structure ◽

Nmr Spectroscopy ◽

Dft Calculations ◽

Palladium Complex ◽

Exafs Spectroscopy ◽

X Ray ◽

Absorption Fine ◽

X Ray Absorption

The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]2 in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments.

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Uranyl Coordination in Ionic Liquids: The Competition between Ionic Liquid Anions, Uranyl Counterions, and Cl-Anions Investigated by Extended X-ray Absorption Fine Structure and UV−Visible Spectroscopies and Molecular Dynamics Simulations

Inorganic Chemistry ◽

10.1021/ic061864+ ◽

2007 ◽

Vol 46 (12) ◽

pp. 4815-4826 ◽

Cited By ~ 60

Author(s):

C. Gaillard ◽

A. Chaumont ◽

I. Billard ◽

C. Hennig ◽

A. Ouadi ◽

...

Keyword(s):

Molecular Dynamics ◽

Ionic Liquid ◽

Ionic Liquids ◽

Fine Structure ◽

Molecular Dynamics Simulations ◽

X Ray ◽

Absorption Fine ◽

Uv Visible ◽

Dynamics Simulations ◽

X Ray Absorption

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Solubilities, Structures, and Speciations of Bimetallic Composite Ionic Liquids: X-ray Absorption Fine Structure and Density Functional Theory Calculations

Industrial & Engineering Chemistry Research ◽

10.1021/acs.iecr.0c06196 ◽

2021 ◽

Author(s):

Yaning Zhang ◽

Rui Zhang ◽

Luo Wu ◽

Haiyan Liu ◽

Zhichang Liu ◽

...

Keyword(s):

Density Functional Theory ◽

Ionic Liquids ◽

Fine Structure ◽

Density Functional ◽

Density Functional Theory Calculations ◽

Functional Theory ◽

X Ray ◽

Absorption Fine ◽

Bimetallic Composite ◽

X Ray Absorption

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Electronic structures of ionic liquids [Cnmim]+BF4- and [Cnmim]+PF6- studied by ultraviolet photoemission, inverse photoemission, and near-edge X-ray absorption fine structure spectroscopies

Chemical Physics Letters ◽

10.1016/j.cplett.2008.01.049 ◽

2008 ◽

Vol 455 (4-6) ◽

pp. 213-217 ◽

Cited By ~ 61

Author(s):

Toshio Nishi ◽

Takashi Iwahashi ◽

Hiroyuki Yamane ◽

Yukio Ouchi ◽

Kaname Kanai ◽

...

Keyword(s):

Ionic Liquids ◽

Fine Structure ◽

Electronic Structures ◽

X Ray ◽

Absorption Fine ◽

Inverse Photoemission ◽

X Ray Absorption

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Applications of X-Ray Absorption Fine Structure to Catalysts and Model Surfaces

Journal de Physique IV (Proceedings) ◽

10.1051/jp4/1997009 ◽

1997 ◽

Vol 7 (C2) ◽

pp. C2-67-C2-81 ◽

Cited By ~ 4

Author(s):

Y. Iwasawa

Keyword(s):

Fine Structure ◽

X Ray ◽

Absorption Fine ◽

Model Surfaces ◽

X Ray Absorption

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EXTENDED X-RAY ABSORPTION FINE STRUCTURE : RECENT DEVELOPMENTS

Le Journal de Physique Colloques ◽

10.1051/jphyscol:1978415 ◽

1978 ◽

Vol 39 (C4) ◽

pp. C4-120-C4-124

Author(s):

P. A. LEE

Keyword(s):

Fine Structure ◽

X Ray ◽

Absorption Fine ◽

Recent Developments ◽

X Ray Absorption

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Structure of magnetic thin films and nanostructures studied by extended X-ray absorption fine structure

Surface Science ◽

10.1016/s0039-6028(00)00087-x ◽

2000 ◽

Vol 454-456 ◽

pp. 723-728 ◽

Cited By ~ 2

Author(s):

H. Magnan ◽

P. Le Fèvre ◽

A. Midoir ◽

D. Chandesris ◽

H. Jaffrès ◽

...

Keyword(s):

Thin Films ◽

Fine Structure ◽

Magnetic Thin Films ◽

X Ray ◽

Absorption Fine ◽

X Ray Absorption

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Movement of Fe with respect to the heme plane in the R-T transition of carp hemoglobin. An extended x-ray absorption fine structure study.

Journal of Biological Chemistry ◽

10.1016/s0021-9258(17)38435-1 ◽

1986 ◽

Vol 261 (13) ◽

pp. 5689-5692 ◽

Cited By ~ 3

Author(s):

M R Chance ◽

L J Parkhurst ◽

L S Powers ◽

B Chance

Keyword(s):

Fine Structure ◽

Structure Study ◽

X Ray ◽

Absorption Fine ◽

X Ray Absorption

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Kinetic analysis of Ag particle redispersion into ZSM-5 in the presence of coke using in situ XAFS

Catalysis Science & Technology ◽

10.1039/d0cy01989e ◽

2021 ◽

Author(s):

Kazumasa Murata ◽

Junya Ohyama ◽

Atsushi Satsuma

Keyword(s):

Fine Structure ◽

Kinetic Analysis ◽

X Ray ◽

Xafs Spectroscopy ◽

Absorption Fine ◽

Ag Particles ◽

In Situ Xafs ◽

Ag Particle ◽

X Ray Absorption

In the present study, the redispersion behavior of Ag particles on ZSM-5 in the presence of coke was observed using in situ X-ray absorption fine structure (XAFS) spectroscopy.

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Backbonding contributions to small molecule chemisorption in a metal–organic framework with open copper(i) centers

Chemical Science ◽

10.1039/d0sc06038k ◽

2021 ◽

Author(s):

Gregory M. Su ◽

Han Wang ◽

Brandon R. Barnett ◽

Jeffrey R. Long ◽

David Prendergast ◽

...

Keyword(s):

Fine Structure ◽

Small Molecule ◽

Metal Organic Framework ◽

X Ray ◽

Metal Site ◽

Absorption Fine ◽

Metal Organic ◽

X Ray Absorption ◽

Organic Framework

In situ near edge X-ray absorption fine structure spectroscopy directly probes unoccupied states associated with backbonding interactions between the open metal site in a metal–organic framework and various small molecule guests.

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