Complexes of 8-Amino-2-methylquinoline with divalent iron, cobalt, nickel, copper, and zinc sulphates

1970 ◽  
Vol 23 (7) ◽  
pp. 1375 ◽  
Author(s):  
MR Litzow ◽  
LF Power ◽  
AM Tait
Keyword(s):  
Infrared Spectra ◽  
Iron Cobalt ◽  
Divalent Iron ◽  
Cobalt Nickel ◽  
Copper And Zinc ◽  
Nickel Copper ◽  
Visible Spectra

The complexes formed by 8-amino-2-methylquinoline (maq) with iron(11), cobalt(11), nickel(11), copper(11), and zinc(11) sulphates have been prepared. The visible spectra, conductivities, and infrared spectra favour the assignment of dimeric octahedral stereochemistries for the copper(11) and zinc(11) complexes, involving ohelating sulphato groups. The complexes of iron(11), nickel(11), and cobalt(11) appear to be octahedral and monomeric with monodentate sulphato groups.

scholarly journals On the Dissolution of Metals in Ionic Liquids 1. Iron, Cobalt, Nickel, Copper, and Zinc

2021 ◽  
Vol 2 (1) ◽  
pp. 63-73
Author(s):  
Jéssica D. S. Vicente ◽  
Domingas C. Miguel ◽  
Afonso M. P. Gonçalves ◽  
Diogo M. Cabrita ◽  
José M. Carretas ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Redox Potential ◽  
Final State ◽  
Iron Cobalt ◽  
Influence Of Temperature ◽  
Dissolution Reaction ◽  
Cobalt Nickel ◽  
Iron Metal ◽  
Copper And Zinc ◽  
Nickel Copper

Ionic liquids are critical reagents for science and technical processes nowadays. Metals are the most used reagents in the industry. It is crucial to have a deeper understanding of how ionic liquids and metals could interact. In this article the interaction of those two families of compounds is accessed. The dissolution (reaction) of metals with ionic liquids is studied, namely the influence of temperature, redox potential, and availability of an oxidant in the process. The final state achieved by the iron metal samples was also addressed by Mössbauer spectroscopy.

Diisothiocyanatotetrapyridine and Diisothiocyanatodipyridine Complexes of Dipositive First-Transition-Metal Ions (Manganese, Iron, Cobalt, Nickel, Copper, and Zinc)

2007 ◽  
pp. 251-256 ◽  
Author(s):  
George B. Kauffman ◽  
Richard A. Albers ◽  
Fred L. Harlan ◽  
R. Scott Stephens ◽  
Ronald O. Ragsdale
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Copper And Zinc ◽  
Nickel Copper

Poly-Bis(Thiocyanato-N)Bis-μ-(1H-1,2,4-Triazole-N2,N4)Metal(II) Complexes with Manganese, Iron, Cobalt, Nickel, Copper and Zinc, and Bis[Tris(Thiocyanato-N)Tris(μ-4H-1,2,4-Triazole-N1)Nickel(II)-N2,N2′,N2″]Nickel(II)

2007 ◽  
pp. 157-161 ◽  
Author(s):  
J. G. Haasnoot ◽  
D. W. Engelfriet ◽  
J. Reedijk ◽  
James T. Cronin ◽  
J. A. Mclaren ◽  
...  
Keyword(s):  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Copper And Zinc ◽  
Nickel Copper

The coordination of β-amino ketoximes with divalent iron, cobalt, nickel and zinc

1978 ◽  
Vol 31 (11) ◽  
pp. 2409 ◽  
Author(s):  
HKJ Powell ◽  
JM Russell
Keyword(s):  
Aqueous Solution ◽  
Hydrogen Bonding ◽  
Stability Constant ◽  
Methyl Ether ◽  
Infrared Spectra ◽  
Iron Cobalt ◽  
Divalent Iron ◽  
Cobalt Nickel ◽  
Stability Order ◽  
The Stability

The iron(II), nickel(II) and zinc(II) complexes of the diamine dioxime ligand 4,4,9,9-tetramethyl-5,8-diazadodecane-2,11-dione dioxime (H2dddo) and the cobalt(II), nickel(II) and zinc(II) complexes of its O-methyl ether (Hddmo) have been studied potentiometrically at 25°C, I 0.10M NaCl. Stability constant data are compared with those obtained for the copper(II) and cobalt(II) complexes of H2dddo and the copper(II) complexes of Hddmo. H2dddo coordinates in the oxime-oximato form [M(Hdddo)]+ with iron(II), cobalt(II), nickel(II) and zinc(II) Hddmo forms complexes with the ligand coordinated in the oxime form [M(Hddmo)]2+ and the oximato form [M(ddmo)]+. The complexes [Zn(Hddmo)2]2+, [Zn(Hddmo)(ddmo)]+ and [Co(ddmo)(OH)] were also characterized in aqueous solution. The stability order FeII < CoII < NiII < CuII > ZnII was observed for the formation of 1 : 1 complexes with the ligands Hdddo- (log K = 8.8, 11.7, 15.2, 23.3, 12.0 for Fe to Zn respectively) and Hddmo (5.7, 6.6, 12.1, 5.3 for Co to Zn). The infrared spectra of the complexes [Ni(Hdddo)] ClO4,H2O and [Zn(Hdddo)] ClO4 are discussed in terms of oxime-oximato hydrogen bonding.

Standards for iron, cobalt, nickel, copper, and zinc in laser microprobe emission spectrometry of biological material

1976 ◽  
Vol 48 (11) ◽  
pp. 1517-1519 ◽  
Author(s):  
Elvio. Giovannini ◽  
Giovanni B. Principato ◽  
Francesco. Rondelli
Keyword(s):  
Biological Material ◽  
Emission Spectrometry ◽  
Iron Cobalt ◽  
Laser Microprobe ◽  
Cobalt Nickel ◽  
Copper And Zinc ◽  
Nickel Copper

Studies of reactions of atomic and diatomic chromium, manganese, iron, cobalt, nickel, copper, and zinc with molecular water at 15 K

1985 ◽  
Vol 89 (16) ◽  
pp. 3541-3547 ◽  
Author(s):  
J. W. Kauffman ◽  
Robert H. Hauge ◽  
J. L. Margrave
Keyword(s):  
Molecular Water ◽  
Iron Cobalt ◽  
Cobalt Nickel ◽  
Copper And Zinc ◽  
Nickel Copper
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