scholarly journals Effect of Interfaces on Dielectric Relaxation in La0.35Sr0.6MnO3 -YSZ

2000 ◽  
Vol 53 (5) ◽  
pp. 715
Author(s):  
Xia Zheng-Cai ◽  
Tang Chao-Qun ◽  
Zhou Dong-Xiang ◽  
Yang Jian-Hui

The perovskite structure material La 0.35 Sr 0.6 MnO 3 was sintered in air and the mixed ceramic of a 0.35 Sr 0.6 MnO 3 and 8 mol % Y 2 O 3 +ZrO 2 with a 1:1 mass rate was also sintered in air, both at 1530 K for 12 hour. The AC complex impedance spectra have been measured and the effect of the interface between La 0.35 Sr 0.6 MnO 3 and YSZ on dielectric relaxation properties of La 0.35 Sr 0.6 MnO 3 has been investigated. A schematic of diffusion phase formation and the equivalent circuits are proposed for explaining the results. In the complex impedance spectra, the first and second semicircles correspond to the grain-boundary and interface respectively. The results show that the dielectric relaxation properties and structure of the mixed ceramic are different to that of single phase La 0.35 Sr 0.6 MnO 3 . The interface has an important effect on the electric properties of the mixed ceramic and produces a dielectric relaxation in low frequency.

1998 ◽  
Vol 12 (11) ◽  
pp. 433-441 ◽  
Author(s):  
P. S. Rama Sastry ◽  
T. Bhimasankaram ◽  
G. S. Kumar ◽  
G. Prasad

Complex impedance spectra of ferroelectric mixed ceramic system ( Na 0.5 Bi 0.5)1-x Ca x Bi 4 Ti 4 O 15 with x=0, 0.1, 0.3, 0.5, 0.7 and 1 was studied as a function of frequency and temperature in the range 1 KHz to 10 MHz and 30°C to 620°C respectively. Equivalent circuits involving resistive and capacitive elements at different temperatures, activation energies of relaxations and conduction were evaluated using impedance plots. A comparative study of impedance and conductivity facilities an insight in understanding the electrical nature of these electroceramics.


2016 ◽  
Vol 30 (02) ◽  
pp. 1550277 ◽  
Author(s):  
Y. P. Jiang ◽  
R. Li ◽  
X. G. Tang ◽  
Q. X. Liu ◽  
D. G. Chen

The influence of nickel doping on the electrical properties and dielectric relaxation in Zn[Formula: see text]Ni[Formula: see text]Fe2O4 (ZNFO, [Formula: see text]) ceramics has been investigated via the dielectric and complex impedance spectra measurements. According to the modified Curie–Weiss law, the diffusivity factor of the ZNFO ceramics from 1.69 to 2.02 with [Formula: see text] increasing from 0.2 to 0.5, respectively. Two relaxation peaks are observed in the nickel doped samples, by employing the modified Arrhenius equation, two activation energy values of different sintering temperatures were calculated and analyzed in combination with oxygen vacancy. The Cole–Cole plots showed that the semicircular arcs which are nonideal Debye type, and the grain boundaries resistance increases with increasing Ni concentration.


2007 ◽  
Vol 336-338 ◽  
pp. 709-711 ◽  
Author(s):  
Hong Jie Zhao ◽  
Ji Zhou ◽  
Zhi Lun Gui ◽  
Long Tu Li

The effects of Bi-substitution on the complex impedance spectra of yttrium iron garnet (YIG) were studied in this paper. The polycrystalline yttrium iron garnet Y2BiFe5O12 (YIG: Bi) and Y3Fe5O12 (YIG) samples were prepared by solid-reaction method. The complex impedance spectra were measured in the frequency range from 1 KHz to 100MHz at several temperatures between 210oC and 500oC. The complex impedance sample shows that the YIG: Bi can be represented by double Cole-Cole semicircles, and the YIG can be represented by a single Cole semicircle. The physical structure of the specimen was visualized as comprising of small resistance grains separated by large resistance grain boundaries in accordance with the impedance spectra observations. The electrical processes in the sample were modeled in the form of an electrical equivalent circuit made up of a series combination of two parallel RC circuits attributed to grains and grain boundaries. The temperature dependence of bulk resistance indicated an evidence of Arrhenius-type thermally activated process, showing a close to linear variation up to a temperature of 740 K.


2016 ◽  
Vol 70 (1) ◽  
pp. 193-200 ◽  
Author(s):  
Tomoko FUKUYAMA ◽  
Yuki OKAMOTO ◽  
Takuya HASEGAWA ◽  
Osamu SENBU

2020 ◽  
Vol 384 (27) ◽  
pp. 126680
Author(s):  
Qiubo Hu ◽  
Dahu Chang ◽  
Jianfeng Su ◽  
Ruirui Sun ◽  
Dongmei Zhang ◽  
...  

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