Construction of a composite-sphere model for molecules of tetrahedral symmetry

2021 ◽  
pp. e1913254
Author(s):  
Franklin Ramos ◽  
Ana Ramos ◽  
Giuseppe Pellicane ◽  
Lloyd L. Lee
2005 ◽  
Vol 69 (3) ◽  
pp. 931-931 ◽  
Author(s):  
Teruhito Miyamoto ◽  
Takeyuki Annaka ◽  
Jiro Chikushi

2005 ◽  
Vol 69 (1) ◽  
pp. 23-29 ◽  
Author(s):  
Teruhito Miyamoto ◽  
Takeyuki Annaka ◽  
Jiro Chikushi

PAMM ◽  
2017 ◽  
Vol 17 (1) ◽  
pp. 581-582 ◽  
Author(s):  
Christian Dammann ◽  
Rolf Mahnken ◽  
Peter Lenz

1993 ◽  
Vol 3 (4) ◽  
pp. 1053-1058 ◽  
Author(s):  
Chen Lu-Jun ◽  
Wang Ning ◽  
Luo Enze
Keyword(s):  

1979 ◽  
Vol 44 (8) ◽  
pp. 2330-2337 ◽  
Author(s):  
Jindřiška Maternová ◽  
Anastas A. Andreev ◽  
Dimitrii M. Shopov ◽  
Karel Setínek

It was found spectroscopically that cobalt(II) acetate dissolved in glacial acetic acid forms the octahedral complex [Co(OAc)2(HOAc)4] which in the presence of bromide ions gives the octahedral [Co(OAc)Br(HOAc)4] and tetrahedral bromo(acetate)cobalt(II) complexes with the higher number of Br- ions. When attached to an organic polymer cobalt(II) ions are bonded in the form of octahedral [Co(H2O)6]2+ cations which form with acetic acid similar complexes as in homogeneous phase and are able to coordinate one bromide ion. Drying the copolymer possessing octahedral hexaaquocobalt(II) cations leads to tetrahedral aquocomplexes which are solvated by gaseous acetic acid and converted into the acetate complexes with the liquid acid. The latter contain the acid in the inner coordination sphere and have tetrahedral symmetry.


1983 ◽  
Vol 38 (4) ◽  
pp. 426-427 ◽  
Author(s):  
Arndt Simon ◽  
Karl Peters ◽  
Harry Hahn

Abstract The structure of the title compound has been determined by X-ray crystallography. The title compound is synthesized from the elements at 600 °C. Its crystal structure, derived from powder data [3] is refined by single crystal diffractometer data. The structure is trigonal (P3̅ml, α = 684.1(1), c = 724.4(1) pm); Pd2+ cations and PS43- anions form a network with an anti-Claudetite (AS2O3) type structure. The PS4 units are distinctly distorted from ideal tetrahedral symmetry. The Pd atoms have a planar environment of 4 S atoms.


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