Synthesis of key intermediate for (+)-tofacitinib through CoIII(salen)-catalyzed two stereocentered hydrolytic kinetic resolution of (±)-methyl-3-(oxiran-2-yl)butanoate

2018 ◽  
Vol 48 (9) ◽  
pp. 1045-1051 ◽  
Author(s):  
Rohit B. Kamble ◽  
Gurunath Suryavanshi
Keyword(s):  
Kinetic Resolution ◽  
Hydrolytic Kinetic Resolution

A Versatile Co(bisalen) Unit for Homogeneous and Heterogeneous Cooperative Catalysis in the Hydrolytic Kinetic Resolution of Epoxides

2009 ◽  
Vol 15 (16) ◽  
pp. 3951-3955 ◽  
Author(s):  
Krishnan Venkatasubbaiah ◽  
Christopher S. Gill ◽  
Tait Takatani ◽  
C. David Sherrill ◽  
Christopher W. Jones
Keyword(s):  
Kinetic Resolution ◽  
Cooperative Catalysis ◽  
Hydrolytic Kinetic Resolution

Synthesis of the Neurokinin 1 Receptor Antagonist (+)-L-733,060 by Jacobsen’s Hydrolytic Kinetic Resolution

2020 ◽  
Vol 56 (12) ◽  
pp. 2159-2164
Author(s):  
D. N. Bhangare ◽  
V. B. Mahale ◽  
R. G. Shinde ◽  
M. D. Nikalje ◽  
S. D. Duthade ◽  
...  
Keyword(s):  
Receptor Antagonist ◽  
Kinetic Resolution ◽  
Neurokinin 1 Receptor ◽  
Hydrolytic Kinetic Resolution ◽  
Neurokinin 1

Aromatic donor–acceptor interaction promoted catalyst assemblies for hydrolytic kinetic resolution of epichlorohydrin

2019 ◽  
Vol 17 (1) ◽  
pp. 172-180 ◽  
Author(s):  
Daniel R. Blechschmidt ◽  
Matthew D. Woodhouse ◽  
Sebastien Inagaki ◽  
Melita Whitfield ◽  
Ayokunnumi Ogunsanya ◽  
...  
Keyword(s):  
Kinetic Resolution ◽  
Catalyst Activity ◽  
Acceptor Interaction ◽  
Hydrolytic Kinetic Resolution ◽  
Aromatic Donor ◽  
Donor Acceptor

The catalyst activity of bis-acceptor functionalized Co(iii)–salen in hydrolytic kinetic resolution can be fine-tuned by introducing a proper donor compound.

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