Curing Kinetics of Liquid Crystalline Epoxy Resins Based on Bisphenol-S Mesogen with DDE by Nonisothermal DSC Data

2009 ◽  
Vol 58 (3) ◽  
pp. 167-177
Author(s):  
Jun-Gang Gao ◽  
Li Huo ◽  
Xiaona Zhang
2013 ◽  
Vol 702 ◽  
pp. 119-122
Author(s):  
Teng Fei Shen ◽  
Fa Chao Wu ◽  
Ying Juan Sun

A series of novel azo-containing twin liquid crystalline (LC) epoxy monomers were cured with anhydrides without extra catalyst and the curing kinetics was investigated by non-isothermal differential scanning calorimetry (DSC) technique. The effect of Azo group on the Curing Kinetics of Epoxy/anhydride System was investigated and the result showed that Azo group served as a catalyst to accelerate the curing reaction. The curing mechanism was confirmed by the UV-Vis spectrum.


1993 ◽  
Vol 13 (4) ◽  
pp. 571-584 ◽  
Author(s):  
C. Carfagna ◽  
E. Amendola ◽  
M. Giamberini ◽  
A. G. Filippov ◽  
R. S. Bauer

Author(s):  
Alice Mititelu ◽  
Thierry Hamaide ◽  
Christian Novat ◽  
Jérôme Dupuy ◽  
Constantin N. Cascaval ◽  
...  

2013 ◽  
Vol 702 ◽  
pp. 115-118
Author(s):  
Teng Fei Shen ◽  
Chun Feng Sun ◽  
Ying Juan Sun

A series of novel azo-containing twin liquid crystalline (LC) epoxy monomers were cured with anhydrides without extra catalyst and the curing kinetics was investigated by non-isothermal differential scanning calorimetry (DSC) technique. The results showed that the effect of phase behavior on activation energy (Ea) was very great. The chemical kinetic control and diffusion control mechanisms dominant the curing together, which gives a larger value of Ea. Azo group also served as a catalyst to accelerate the curing reaction.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1302
Author(s):  
Younggi Hong ◽  
Munju Goh

Epoxy resin (EP) is one of the most famous thermoset materials. In general, because EP has a three-dimensional random network, it possesses thermal properties similar to those of a typical heat insulator. Recently, there has been substantial interest in controlling the network structure of EP to create new functionalities. Indeed, the modified EP, represented as liquid crystalline epoxy (LCE), is considered promising for producing novel functionalities, which cannot be obtained from conventional EPs, by replacing the random network structure with an oriented one. In this paper, we review the current progress in the field of LCEs and their application to highly thermally conductive composite materials.


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