New nanobidentate Schiff base ligand of 2-aminophenol with 2-acetyl ferrocene with some lanthanide metal ions: synthesis, characterization and Hepatitis A, B, C and breast cancer docking studies

2017 ◽  
Vol 70 (20) ◽  
pp. 3552-3574 ◽  
Author(s):  
Walaa H. Mahmoud ◽  
Nessma F. Mahmoud ◽  
Gehad G. Mohamed
2017 ◽  
Vol 14 (1) ◽  
pp. 135-147
Author(s):  
Baghdad Science Journal

The free Schiff base ligand (HL1) is prepared by being mixed with the co-ligand 1, 10-phenanthroline (L2). The product then is reacted with metal ions: (Cr+3, Fe+3, Co+2, Ni+2, Cu+2 and Cd+2) to get new metal ion complexes. The ligand is prepared and its metal ion complexes are characterized by physic-chemical spectroscopic techniques such as: FT-IR, UV-Vis, spectra, mass spectrometer, molar conductivity, magnetic moment, metal content, chloride content and microanalysis (C.H.N) techniques. The results show the formation of the free Schiff base ligand (HL1). The fragments of the prepared free Schiff base ligand are identified by the mass spectrometer technique. All the analysis of ligand and its metal complexes are in good agreement with the theoretical values indicating the purity of Schiff base ligand and the metal complexes. From the above data, the molecular structures for all the metal complexes are proposed to be octahedral


2020 ◽  
Vol 7 (2) ◽  
pp. 464-469 ◽  
Author(s):  
Jieni Liu ◽  
Ting Zhu ◽  
Xiaoping Yang ◽  
Hongfen Chen ◽  
Dongliang Shi ◽  
...  

A 1-D coordination polymer [Sm(HL)2(NO3)]n was constructed using a new flexible Schiff base ligand that has a long-chain (CH2)10 backbone, and it shows dual-emissive response to metal ions, especially to Co2+ at the ppm level.


2019 ◽  
Vol 18 (11) ◽  
pp. 2717-2729 ◽  
Author(s):  
Sudipto Dey ◽  
Ashim Maity ◽  
Milan Shyamal ◽  
Debasish Das ◽  
Samir Maity ◽  
...  

A 2,6-diformyl-p-cresol (DFC)-4-amino antipyrine (AP) based dual signaling fluorescent Schiff base ligand (DFCAP) is found to exhibit colorimetric and fluorescence turn on selective sensing towards metal ions, Zn2+ and Al3+.


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