Preparation and characterization of PEPPSI-palladium N-heterocyclic carbene complexes using benzimidazolium salts catalyzed Suzuki–Miyaura cross coupling reaction and their antitumor and antimicrobial activities

2019 ◽  
Vol 72 (3) ◽  
pp. 516-527 ◽  
Author(s):  
Lamia Boubakri ◽  
Khaireddine Dridi ◽  
Abdullah Sulaiman Al-Ayed ◽  
İsmail Özdemir ◽  
Sedat Yasar ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Antimicrobial Activities ◽  
Carbene Complexes ◽  
Cross Coupling Reaction ◽  
Benzimidazolium Salts

Pyridin- and quinolinylidene nickel carbene complexes as effective catalysts for the Grignard cross-coupling reaction

2007 ◽  
Vol 265 (1-2) ◽  
pp. 50-58 ◽  
Author(s):  
Sabine K. Schneider ◽  
Christoph F. Rentzsch ◽  
Anneke Krüger ◽  
Helgard G. Raubenheimer ◽  
Wolfgang A. Herrmann
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Carbene Complexes ◽  
Cross Coupling Reaction

Design, preparation and characterization of aerogel NiO–CuO–CoO/SiO2 nanocomposite as a reusable catalyst for C–N cross-coupling reaction

2020 ◽  
Vol 44 (13) ◽  
pp. 5056-5063
Author(s):  
Amir Hossein Ghasemi ◽  
Hossein Naeimi
Keyword(s):  
Sol Gel ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Supercritical Drying ◽  
Reusable Catalyst ◽  
Drying Method ◽  
Cross Coupling Reaction ◽  
Powerful Process

The aerogel nanocomposite produces using the sol–gel and supercritical drying method processes. The CO2 supercritical drying (SCD) was taken as the most powerful process, ensuring the best properties of the product.

Design and Synthesis of New Conjugated Porphyrin Copolymers for Optical-Electronic Applications

1997 ◽  
Vol 488 ◽  
Author(s):  
Biwang Jiang ◽  
Szu-Wei Yang ◽  
Phuong T. Lam ◽  
Wayne E. Jones
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Electronic Coupling ◽  
Alkyl Ether ◽  
Design And Synthesis ◽  
Cross Coupling Reaction ◽  
Enhanced Solubility ◽  
Palladium Catalyzed ◽  
Porphyrin Polymers

AbstractNew linear conjugated porphyrin polymers were synthesized by a palladium-catalyzed cross-coupling reaction of [5,15-bis(ethynyl)-10,20-bis (mesityl)porphyrin]zinc and diiodobenzene derivatives. Enhanced solubility of the conjugated porphyrin polymers was achieved by attachment of long alkyl ether or dialkyl amide groups to the aryl moiety, resulting in unambiguous characterization by 1H NMRLR, GPC, UV-Vis and fluorescence spectroscopies. The introduction of alkyl ether (electron donor) or dialkyl amide (electron acceptor) results in significant modulation of the electronic properties of the conjugated porphyrin polymers due to strong electronic coupling. The spectroscopic and electronic characterization of these materials provides for comparison to earlier preparations of ethynyl bridged conjugated copolymers in which electronic coupling was substantially weaker.

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