Enhancement of adsorption and anticorrosion performance of two polymeric compounds for the corrosion of SABIC carbon steel in hydrochloric acid

Author(s):  
M. Abdallah ◽  
Arej S. Al-Gorair ◽  
A. Fawzy ◽  
H. Hawsawi ◽  
R. S. Abdel Hameed
2018 ◽  
Vol 10 (1) ◽  
pp. 102-115
Author(s):  
Cinthia E. B. Maia ◽  
Gilberto A. Romeiro ◽  
Márcia C. C. Veloso ◽  
Mariane F. dos Santos ◽  
Marcos V. da Silva Santana ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3535
Author(s):  
Naba Jasim Mohammed ◽  
Norinsan Kamil Othman ◽  
Mohamad Fariz Mohamad Taib ◽  
Mohd Hazrie Samat ◽  
Solhan Yahya

Extracts from plant materials have great potential as alternatives to inorganic corrosion inhibitors, which typically have harmful consequences. Experimental and theoretical methodologies studied the effectiveness of agricultural waste, namely, date palm seed extract as a green anti-corrosive agent in 0.5 M hydrochloric acid. Experimental results showed that immersion time and temperature are closely related to the effectivity of date palm seed as a corrosion inhibitor. The inhibition efficiency reduced from 95% to 91% at 1400 ppm when the immersion time was increased from 72 h to 168 h. The experimental results also indicated that the inhibition efficiency decreased as the temperature increased. The presence of a protective layer of organic matter was corroborated by scanning electron microscopy. The adsorption studies indicated that date palm seed obeyed Langmuir adsorption isotherm on the carbon steel surface, and Gibbs free energy values were in the range of −33.45 to −38.41 kJ·mol−1. These results suggested that the date palm seed molecules interacted with the carbon steel surface through mixture adsorption. Theoretical calculations using density functional theory showed that the capability to donate and accept electrons between the alloy surface and the date palm seed inhibitor molecules is critical for adsorption effectiveness. The HOMO and LUMO result indicated that the carboxyl (COOH) group and C=C bond were the most active sites for the electron donation-acceptance type of interaction and most auxiliary to the adsorption process over the Fe surface.


RSC Advances ◽  
2017 ◽  
Vol 7 (40) ◽  
pp. 24576-24588 ◽  
Author(s):  
H. S. Gadow ◽  
M. M. Motawea

The inhibitive effect and adsorption behavior of ginger roots extract (GRE) on the corrosion of carbon steel in 1.0 M HCl solution at different temperatures were investigated.


2011 ◽  
Vol 301-303 ◽  
pp. 109-115
Author(s):  
Lin Lin Liu ◽  
Yuan Li ◽  
Bao Wei Hao ◽  
Shi Zhao Wang

Little attention has been paid to the nano-TiO2as corrosion inhibitor before. In this paper, Myristic acid-modified nano-TiO2(MA-TiO2) were synthesized by Myristic acid and tetrabutyl titanate via the sol-gel method, and it was characterized by IR and TEM. MA-TiO2was dispersed in oil, and used as a corrosion inhibitor. From the Tafel plots and EIS spectra, we can know that the values of the current densities decreased by the addition of MA-TiO2. Because of the MA-TiO2formed a deposition layer in the surface of 45#carbon steel panels, the current density of the the base oil with MA-TiO2is much smaller than the base oil. The inhibition efficiency was over 90% with added 5 wt % TiO2.


2021 ◽  
Vol 180 ◽  
pp. 109195
Author(s):  
K. Kousar ◽  
M.S. Walczak ◽  
T. Ljungdahl ◽  
A. Wetzel ◽  
H. Oskarsson ◽  
...  

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