Time-resolved Total Internal Reflection Raman Scattering Study on Electric-Field-Induced Reorientation Dynamics of Nematic Liquid Crystal of 4-Hexyl-4′-Cyanobiphenyl

Author(s):  
T. Morikawa ◽  
E. Shirai ◽  
J. Tanno ◽  
H. Takanashi ◽  
A. Yasuda ◽  
...  
2013 ◽  
Vol 2013 ◽  
pp. 1-13 ◽  
Author(s):  
S. V. Pasechnik ◽  
A. V. Dubtsov ◽  
D. V. Shmeliova ◽  
D. A. Semerenko ◽  
V. G. Chigrinov ◽  
...  

The phenomenological torque balance model previously introduced to describe the electrically assisted light-induced gliding is generalized to study the reorientation dynamics of the nematic liquid crystal easy axis at photoaligned azo-dye films under the combined action of in-plane electric field and reorienting UV light linearly polarized at varying polarization azimuth,φp. We systematically examine the general properties of the torque balance model by performing analysising the bifurcations of equilibria at different values of the polarization azimuth and apply for the model to interpret the experimental results. These involve observation of the pronounced purely photoinduced reorientation atφp≠0, as opposed to the case where the light polarization vector is parallel to the initial easy axis (φp=0), and the reorientation is almost entirely suppressed. In the regions between electrodes with nonzero electric field, the effects described by the model are that (a) the dynamics of reorientation slows down withφpand (b) the sense of easy axis rotation is independent of the sign ofφp.


1993 ◽  
Vol 47 (9) ◽  
pp. 1390-1393 ◽  
Author(s):  
H. Sasaki ◽  
M. Ishibashi ◽  
A. Tanaka ◽  
N. Shibuya ◽  
R. Hasegawa

A two-dimensional infrared (2D IR) spectrometer has been modified by the following methods to solve several problems on the 2D IR spectroscopy of electric-field-induced reorientation dynamics of a mixed nematic liquid crystal: (1) The response of the liquid crystal (LC) to an electric field was stabilized by an amplitude-modulated ac electric field. (2) Formulation of an anti-reflection coating (ARC) has been proposed to suppress the interference caused by multiple reflections between IR liquid crystal cell windows. (3) The Fourier transform procedure has been modified to correct the phase of the dynamic difference interferograms without spectral anomalies. These modifications can provide a better signal-to-noise ratio and reproducible 2D IR spectrum of a mixed nematic liquid crystal.


2010 ◽  
Vol 105 (2) ◽  
Author(s):  
Min Sang Park ◽  
Beom-Jin Yoon ◽  
Jung Ok Park ◽  
Veena Prasad ◽  
Satyendra Kumar ◽  
...  

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