Electronic shielding of the crystalline electric field in rare earth ions

The theory that has been developed for rare-earth ions in crystals is here applied to the double nitrates. The paramagnetic resonance data and certain spectroscopic properties of the different rare-earth double nitrates, depending as they do on the crystalline electric field at a rare-earth ion, are related to the six parameters through which the field is defined. It is found that most of the experimental results can be fitted to values of the parameters that vary in a systematic fashion along the rare-earth series.

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Analytical results for crystalline electric field eigenvalues of trivalent rare-earth ions using computer algebra: application to the magnetism of PrX2 (X = Mg, Al, Ru, Rh, Pt)

Journal of Magnetism and Magnetic Materials ◽

10.1016/0304-8853(94)90204-6 ◽

1994 ◽

Vol 137 (1-2) ◽

pp. 186-190 ◽

Cited By ~ 1

Author(s):

R.R. Sobral ◽

A.P. Guimarães ◽

X.A. da Silva

Keyword(s):

Rare Earth ◽

Electric Field ◽

Computer Algebra ◽

Rare Earth Ions ◽

Crystalline Electric Field ◽

Analytical Results ◽

Trivalent Rare Earth

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Investigations into the Origin of the Crystalline Electric Field Effects on Rare Earth Ions: II. Contributions from the Rare Earth Orbitals

Proceedings of the Physical Society ◽

10.1088/0370-1328/82/1/307 ◽

1963 ◽

Vol 82 (1) ◽

pp. 47-57 ◽

Cited By ~ 44

Author(s):

D K Ray

Keyword(s):

Rare Earth ◽

Electric Field ◽

Rare Earth Ions ◽

Crystalline Electric Field ◽

Electric Field Effects ◽

Field Effects ◽

The Rare Earth

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Effect of the ligand charge distribution on the crystalline electric field of rare-earth ions

Proceedings of the Physical Society ◽

10.1088/0370-1328/90/3/329 ◽

1967 ◽

Vol 90 (3) ◽

pp. 839-846 ◽

Cited By ~ 21

Author(s):

A K Raychaudhuri ◽

D K Ray

Keyword(s):

Rare Earth ◽

Electric Field ◽

Charge Distribution ◽

Rare Earth Ions ◽

Crystalline Electric Field

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Investigation into the Origin of Crystalline Electric Field Effects on Rare Earth Ions: I. Contribution from Neighbouring Induced Moments

Proceedings of the Physical Society ◽

10.1088/0370-1328/81/4/307 ◽

1963 ◽

Vol 81 (4) ◽

pp. 663-676 ◽

Cited By ~ 109

Author(s):

M T Hutchings ◽

D K Ray

Keyword(s):

Rare Earth ◽

Electric Field ◽

Rare Earth Ions ◽

Crystalline Electric Field ◽

Electric Field Effects ◽

Field Effects

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Crystalline electric field at the rare-earth sites in RxY1 - xCo5 + y compounds (R = Dy and Tb)

Journal of Magnetism and Magnetic Materials ◽

10.1016/0304-8853(92)90070-5 ◽

1992 ◽

Vol 115 (2-3) ◽

pp. 281-286 ◽

Cited By ~ 2

Author(s):

Han Xiu-feng ◽

Jin Han-min ◽

Chen Hong ◽

Guo Guang-hua ◽

Zhao Tie-song

Keyword(s):

Rare Earth ◽

Electric Field ◽

Crystalline Electric Field ◽

The Rare Earth

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High-Field Magnetization Process and Crystalline Electric Field Interaction in Rare-Earth Permanent-Magnet Materials

Materials Science in Static High Magnetic Fields - Advances in Materials Research ◽

10.1007/978-3-642-56312-6_10 ◽

2002 ◽

pp. 135-148 ◽

Cited By ~ 1

Author(s):

H. Kato ◽

T. Miyazaki ◽

M. Motokawa

Keyword(s):

Rare Earth ◽

Electric Field ◽

Permanent Magnet ◽

High Field ◽

Magnetization Process ◽

Crystalline Electric Field ◽

Field Interaction ◽

Field Magnetization ◽

High Field Magnetization ◽

Permanent Magnet Materials

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Determination of the crystalline electric field in the tetragonal symmetry rare earth intermetallic HoAg2

Journal of Magnetism and Magnetic Materials ◽

10.1016/0304-8853(93)90503-t ◽

1993 ◽

Vol 119 (1-2) ◽

pp. 59-68 ◽

Cited By ~ 11

Author(s):

P. Morin ◽

J.A. Blanco

Keyword(s):

Rare Earth ◽

Electric Field ◽

Tetragonal Symmetry ◽

Crystalline Electric Field ◽

Rare Earth Intermetallic

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CALCULATION OF THE CRYSTAL FIELD IN CeZn2

Modern Physics Letters B ◽

10.1142/s0217984996001668 ◽

1996 ◽

Vol 10 (29) ◽

pp. 1471-1476

Author(s):

MIRCEA ANDRECUT

Keyword(s):

Rare Earth ◽

Intermetallic Compound ◽

Electric Field ◽

Temperature Dependence ◽

Least Squares ◽

Crystal Field ◽

Crystalline Electric Field ◽

Experimental Values ◽

Good Agreement ◽

Rare Earth Intermetallic

The temperature dependence of the second-order crystalline electric field (CEF) parameters of rare earth intermetallic compound CeZn 2 was deduced from the least-squares nonlinear fit to the reciprocal paramagnetic susceptibility along principal crystalline axes. The results of the calculation are in good agreement with the experimental values.

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