Selection and suppression of soft x-ray spectral features using optimized multilayer coatings

2000 ◽  
Vol 3 (1) ◽  
pp. 61-66
Author(s):  
A G Michette ◽  
Z Wang
Metals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1153
Author(s):  
Ivan Pavlenko ◽  
Jozef Zajac ◽  
Nadiia Kharchenko ◽  
Ján Duplák ◽  
Vitalii Ivanov ◽  
...  

This article deals with improving the wear resistance of multilayer coatings as a fundamental problem in metal surface treatment, strengthening elements of cutting tools, and ensuring the reliability of machine parts. It aims to evaluate the wear depth for multilayer coatings by the mass loss distribution in layers. The article’s primary purpose is to develop a mathematical method for assessing the value of wear for multilayer steel-based coatings. The study material is a multilayer coating applied to steel DIN C80W1. The research was performed using up-to-date laboratory equipment. Nitrogenchroming has been realized under overpressure in two successive stages: nitriding for 36 h at temperature 540 °C and chromizing during 4 h at temperature 1050 °C. The complex analysis included several options: X-ray phase analysis, local micro-X-ray spectral analysis, durometric analysis, and determination of wear resistance. These analyses showed that after nitrogenchroming, the three-layer protective coating from Cr23C6, Cr7C3, and Cr2N was formed on the steel surface. Spectral analysis indicated that the maximum amount of chromium 92.2% is in the first layer from Cr23C6. The maximum amount of carbon 8.9% characterizes the layer from Cr7C3. Nitrogen is concentrated mainly in the Cr2N layer, and its maximum amount is 9.4%. Additionally, it was determined that the minimum wear is typical for steel DIN C80W1 after nitrogenchroming. The weight loss of steel samples by 25 mg was obtained. This value differs by 3.6% from the results evaluated analytically using the developed mathematical model of wear of multilayer coatings after complex metallization of steel DIN C80W1. As a result, the impact of the loading mode on the wear intensity of steel was established. As the loading time increases, the friction coefficient of the coated samples decreases. Among the studied samples, plates from steel DIN C80W1 have the lowest friction coefficient after nitrogenchroming. Additionally, a linear dependence of the mass losses on the wearing time was obtained for carbide and nitride coatings. Finally, an increase in loading time leads to an increase in the wear intensity of steels after nitrogenchroming. The achieved scientific results are applicable in developing methods of chemical-thermal treatment, improving the wear resistance of multilayer coatings, and strengthening highly loaded machine parts and cutting tools.


1999 ◽  
Vol 28 (1) ◽  
pp. 1-13
Author(s):  
D. Bhattacharyya ◽  
N. C. Das ◽  
A. P. Roy ◽  
R. Chitra ◽  
S. Basu
Keyword(s):  

2019 ◽  
Vol 19 (1) ◽  
pp. 554-561 ◽  
Author(s):  
Catherine Burcklen ◽  
Regina Soufli ◽  
Jennifer Rebellato ◽  
Christopher Walton ◽  
Evgueni Meltchakov ◽  
...  
Keyword(s):  

1999 ◽  
Author(s):  
Adrian Ivan ◽  
Ricardo J. Bruni ◽  
Kyung Wha Byun ◽  
Finn E. Christensen ◽  
Paul Gorenstein ◽  
...  

Author(s):  
F. E. Christensen ◽  
K. D. Joensen ◽  
P. Gorenstein ◽  
W. C. Priedhorsky ◽  
N. J. Westergaard ◽  
...  
Keyword(s):  

1990 ◽  
Vol 206 ◽  
Author(s):  
Donald R. Huffman ◽  
Wolfgang Krätschmer

ABSTRACTIn May of 1990, crystals of a new form of carbon were observed crystallizing from a solution of the newly-produced macroscopic quantities of fullerene molecules. This discovery followed many years of work we had done in producing and measuring the optical properties of small particles of graphitic carbon, a work which was aimed, in part, at a better understanding of the various spectral features of interstellar material. Among three distinctly different types of carbon particulates, distinguished by their differing ultraviolet and Raman spectra, was one that later proved to contain macroscopic quantities of C60 and C70. Evidence for fullerenes came from mass spectra, infrared spectra, and X-ray and electron diffraction. More, recent experiments with our collaborators have included scanning tunneling microscopy and gas phase emission spectroscopy in the infrared. At the moment, there is no obvious connection with interstellar spectral features.


2009 ◽  
Vol 16 (2) ◽  
pp. 247-259 ◽  
Author(s):  
Jens Kruse ◽  
Peter Leinweber ◽  
Kai-Uwe Eckhardt ◽  
Frauke Godlinski ◽  
Yongfeng Hu ◽  
...  

Synchrotron-based X-ray absorption near-edge structure (XANES) spectroscopy is becoming an increasingly used tool for the element speciation in complex samples. For phosphorus (P) almost all XANES measurements have been carried out at the K-edge. The small number of distinctive features at the P K-edge makes in some cases the identification of different P forms difficult or impossible. As indicated by a few previous studies, the P L 2,3-edge spectra were richer in spectral features than those of the P K-edge. However, experimentally consistent spectra of a wide range of reference compounds have not been published so far. In this study a library of spectral features is presented for a number of mineral P, organic P and P-bearing minerals for fingerprinting identification. Furthermore, the effect of radiation damage is shown for three compounds and measures are proposed to reduce it. The spectra library provided lays a basis for the identification of individual P forms in samples of unknown composition for a variety of scientific areas.


2016 ◽  
Vol 337 (4-5) ◽  
pp. 507-511
Author(s):  
M. Mizumoto ◽  
K. Ebisawa ◽  
M. Tsujimoto ◽  
H. Inoue

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