scholarly journals Thermodynamic modeling of the gas-plasma phase in the processing of radioactive graphite in a gas plasma furnace

2020 ◽  
Vol 1675 ◽  
pp. 012108
Author(s):  
N M Barbin ◽  
A M Kobelev ◽  
D I Terent’ev
Author(s):  
Nikolaiy M. Barbin ◽  
Anton M. Kobelev ◽  
Dmiriy I. Terent’ev ◽  
Sergeiy G. Alexeev

The behavior of radioactive graphite was studied by the method of thermodynamic modeling at high temperature in water vapor. The distribution of radioactive carbon and uranium on phase states is given.


2017 ◽  
Vol 59 (5) ◽  
pp. 507-511 ◽  
Author(s):  
N. M. Barbin ◽  
A. M. Kobelev ◽  
D. I. Terent’ev ◽  
S. G. Alekseev

2014 ◽  
Vol 23 (10) ◽  
pp. 38-47 ◽  
Author(s):  
N. M. BARBIN ◽  
◽  
A. M. KOBELEV ◽  
D. I. TERENTYEV ◽  
S. G. ALEXEEV ◽  
...  

2014 ◽  
Vol 23 (3) ◽  
pp. 58-67 ◽  
Author(s):  
N. M. BARBIN ◽  
◽  
D. I. TERENTIEV ◽  
A. V. PESHKOV ◽  
S. G. ALEXEEV ◽  
...  

2014 ◽  
Vol 23 (12) ◽  
pp. 34-44 ◽  
Author(s):  
N. M. BARBIN ◽  
◽  
M. R. SHAVALEEV ◽  
D. I. TERENTYEV ◽  
S. G. ALEXEEV ◽  
...  

2020 ◽  
Author(s):  
Nikolaj Mihajlovich Barbin ◽  
Anton Mihajlovich Kobelev ◽  
Dmitrij Ivanovich Terent'ev ◽  
Sergej Gennad'evich Alekseev

Behavior of U, Pu radionuclides was investigated when heating radioactive graphite in NaCl – KCl – Na2CO3 – K2CO3 melt with NiO additives using the thermodynamic modeling method. Calculations were made by the TERRA software that is used for the determination of phase composition, thermodynamic and transport properties, taking into account chemical and phase changes in temperature range 373 – 3273 K. Calculation of equilibrium phase composition and parameters of equilibrium was carried out using reference information about properties of the individual substances (INVATERMO, HSC, etc.). This study demonstrates that at a temperature of 1273 K the condensed carbon burns down with the formation of CO and CO2. Increasing temperature to 1673 K causes the condensed compounds of uranium to evaporate. This study determined that uranium exists in the form of ionized UO−3 in temperature range from 1673 to 3273 K. Plutonium exists in the form of gaseous PuO2, PuO in temperature range 2373 – 3273 K. Keywords: thermodynamic modeling, radionuclides, radioactive graphite


2018 ◽  
Vol 56 (5) ◽  
pp. 751-763
Author(s):  
N. Barbin ◽  
◽  
T. Kolbin ◽  
D. Terentyev ◽  
S. Alekseev ◽  
...  

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