Thermodynamics and phase diagram calculation of the binary arsenic-tellurium system in the framework of the generalized lattice model

Abstract In this work we describe how to efficiently calculate thermodynamic properties and T-x diagram of binary As-Te solution in the generalized lattice model. All the thermodynamic parameters of the As-Te solution are obtained within framework of the generalized lattice model. The binary phase diagram of As-Te system is calculated and good agreement with experimental data is obtained.

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High Temperature Thermodynamic Properties and Pseudo-Binary Phase Diagram of the Pb(Zn1/3Nb2/3)0.91Ti0.09O3–PbO System

Japanese Journal of Applied Physics ◽

10.1143/jjap.40.4604 ◽

2001 ◽

Vol 40 (Part 1, No. 7) ◽

pp. 4604-4610 ◽

Cited By ~ 15

Author(s):

Ming Dong ◽

Zuo-Guang Ye

Keyword(s):

Phase Diagram ◽

High Temperature ◽

Thermodynamic Properties ◽

Binary Phase Diagram ◽

Binary Phase

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Considerations on the Kaufman approach to binary phase diagram calculation

Metallurgical Transactions A ◽

10.1007/bf02646847 ◽

1975 ◽

Vol 6 (10) ◽

pp. 1843-1848 ◽

Cited By ~ 16

Author(s):

K. F. Michaels ◽

W. F. Lange ◽

J. R. Bradley ◽

H. I. Aaronson

Keyword(s):

Phase Diagram ◽

Binary Phase Diagram ◽

Phase Diagram Calculation ◽

Binary Phase

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Some useful relationships between the thermodynamic properties and binary phase diagram involving an intermediate compound

Calphad ◽

10.1016/0364-5916(89)90038-2 ◽

1989 ◽

Vol 13 (1) ◽

pp. 53-60 ◽

Cited By ~ 1

Author(s):

Li Rui-Qing ◽

Chou Kuo-Chih

Keyword(s):

Phase Diagram ◽

Thermodynamic Properties ◽

Binary Phase Diagram ◽

Intermediate Compound ◽

Binary Phase

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A Thermodynamic Database for Fe-Cr-Mn-Ni-Ti-S-C-N System

Materials Science Forum ◽

10.4028/www.scientific.net/msf.500-501.711 ◽

2005 ◽

Vol 500-501 ◽

pp. 711-718 ◽

Cited By ~ 8

Author(s):

Katsunari Oikawa ◽

Hajime Mitsui ◽

Kiyohito Ishida

Keyword(s):

Complex System ◽

Experimental Data ◽

Phase Diagram ◽

Thermodynamic Properties ◽

Stainless Steels ◽

Carbon Steels ◽

Thermodynamic Database ◽

Low Carbon ◽

Low Carbon Steels ◽

Good Agreement

A database for thermodynamic information of sulfides and carbo-sulfide in steels has been developed, where the thermodynamic properties of the relevant constituting sub-system of the complex system have been assessed by the CALPHAD (Calculation of Phase Diagrams) approach. The utility of this database is demonstrated in examples of phase diagram calculations of low carbon steels and stainless steels. The calculated results are in good agreement with experimental data. The developed thermodynamic database would be useful in predicting the formation of sulfides and carbo-sulfides in the commercial steels.

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Thermodynamics and phase diagram calculation of some sections in the Ag-Bi-Sn system

Journal of the Serbian Chemical Society ◽

10.2298/jsc0709901z ◽

2007 ◽

Vol 72 (8-9) ◽

pp. 901-909 ◽

Cited By ~ 1

Author(s):

Dragana Zivkovic ◽

Iwao Katayama ◽

Dragan Manasijevic ◽

Hiromi Yamashita ◽

Nada Strbac

Keyword(s):

Experimental Data ◽

Phase Diagram ◽

Thermodynamic Properties ◽

Phase Diagrams ◽

Enthalpy Of Formation ◽

Thermodynamic Functions ◽

Excess Energy ◽

Phase Diagram Calculation ◽

Calculated Phase ◽

Activity Diagrams

The thermodynamic properties and characteristic phase diagrams of some sections in the Ag-Bi-Sn system were calculated. The thermodynamic functions, such as Gibbs excess energy, activity and enthalpy of formation, were calculated using the RKM model and compared with experimental data reported in the literature. Iso-activity diagrams for all three components at 900 K have been constructed. The calculated phase diagrams of the vertical sections Sn-AgBi, Ag-BiSn and Bi-AgSn, obtained using the ThermoCalc program, were compared and confirmed with the results of DTA measurements from the present work. .

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Application of Graham Scan Algorithm in Binary Phase Diagram Calculation

Journal of Phase Equilibria and Diffusion ◽

10.1361/154770306x97137 ◽

2006 ◽

Vol 27 (2) ◽

pp. 121-125

Author(s):

Shuang-Lin Chen ◽

Jie-Yu Zhang ◽

Xiong-Gang Lu ◽

Kuo-Chih Chou ◽

Y. Austin Chang

Keyword(s):

Phase Diagram ◽

Binary Phase Diagram ◽

Phase Diagram Calculation ◽

Binary Phase

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Application of Graham scan algorithm in binary phase diagram calculation

Journal of Phase Equilibria and Diffusion ◽

10.1007/s11669-006-0034-y ◽

2006 ◽

Vol 27 (2) ◽

pp. 121-125 ◽

Cited By ~ 15

Author(s):

Shuang-Lin Chen ◽

Jie-Yu Zhang ◽

Xiong-Gang Lu ◽

Kuo-Chih Chou ◽

Y. Austin Chang

Keyword(s):

Phase Diagram ◽

Binary Phase Diagram ◽

Phase Diagram Calculation ◽

Binary Phase

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Thermodynamic Properties and Phase Equilibria in the Ternary Cu-Pb-Fe System

Archives of Metallurgy and Materials ◽

10.2478/amm-2013-0033 ◽

2013 ◽

Vol 58 (2) ◽

pp. 541-548 ◽

Cited By ~ 4

Author(s):

B. Onderka ◽

D. Jendrzejczyk-Handzlik ◽

K. Fitzner

Keyword(s):

Experimental Data ◽

Phase Diagram ◽

Thermodynamic Properties ◽

Phase Equilibria ◽

Thermodynamic Functions ◽

Binary Systems ◽

Liquid Solution ◽

Calculated Diagram ◽

Calculated Equilibrium ◽

Good Agreement

Using experimental data available in the literature, two binary systems, namely Cu-Pb and Fe-Pb were recalculated. Next, accepting Cu-Fe phase diagram assessment as given by Ansara and Jansson, the ternary Cu-Fe-Pb system was analyzed. Calculated equilibrium lines and thermodynamic functions are compared with existing experimental data. Good agreement was found between the calculated diagram and the experimental results. Having the system optimized, functional dependences of the logarithms of the activity coefficients on temperature and concentrations for Cu, Fe and Pb in the liquid solution are given.

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