scholarly journals Catalytic activity of hierarchical structure based on Ni-Al layered double hydroxide

Author(s):  
A Aliev ◽  
Z Sharafieva ◽  
A Popkov ◽  
D Isakov ◽  
D Sultanaliev
CrystEngComm ◽  
2022 ◽  
Author(s):  
Meng Ya Yang ◽  
Rong Zhao ◽  
Yi Liu ◽  
Hua Lin

In this work, high efficient electrocatalyst Fe-Ni2P/N-GO with hierarchical structure was developed through phosphating NiFe-based layered double hydroxide (LDH) supported by N-doped graphene oxide (GO), which was assembled by the...


2014 ◽  
Vol 672-674 ◽  
pp. 613-618
Author(s):  
Feng Li Yu ◽  
Yang Lu

Heteropolyanion substituted layered double hydroxide were synthesized and used as catalysts for oxidative desulfurization in simulated fuel oil (dibenzothiophene (DBT) inn-octane) or diesel. The catalysts are recoverable and operate with high conversion efficiency under mild conditions of atmospheric pressure and 60 °C in a biphasic system using peroxide hydrogen as oxidant and acetonitrile as extractant. Zn9Al3(OH)24PW12O40(ZnAlPW), Zn9Al3(OH)24PMo12O40(ZnAlPMo) and Zn12Al4(OH)32SiW12O40(ZnAlSiW) were identified as effective catalysts for the oxidative removal of DBT from simulated fuel oil. The order of decreasing catalytic activity is ZnAlPMo > ZnAlPW > ZnAlSiW. The results show that the best catalysts, ZnAlPMo, attained to a DBT conversion of nearly 100%. All the catalysts can be readily recycled by filtration after use. The recoverable ZnAlPMo retains nearly the same catalytic activity as the fresh. ZnAlPMo was found to exhibit an ideal catalytic activity in oxidative desulfurization of diesel with a total sulfur removal rate of 91.8%.


2007 ◽  
Vol 61 (2) ◽  
Author(s):  
Z. Mikulová ◽  
P. Čuba ◽  
J. Balabánová ◽  
T. Rojka ◽  
F. Kovanda ◽  
...  

AbstractThe effect of hydrothermal treatment on properties (crystallinity, porous structure, reducibility, acidity, basicity, and catalytic activity and selectivity in toluene and ethanol total oxidation) of Ni—Al layered double hydroxide precursors and related mixed oxides was examined. The hydrothermal treatment increased considerably both the content of crystalline phase and LDH crystallite size. On the other hand, only a slight effect of the precursor hydrothermal treatment on crystallinity of the related Ni—Al mixed oxides obtained by calcination at 450°C was observed. The reducibility of NiO particles appeared to be hindered considerably compared to the reducibility of pure NiO. Catalytic activity of the Ni—Al mixed oxides prepared from the precursors hydrothermally treated for a short time (4 h) was the highest. The highest amount of acetaldehyde formed during the total oxidation of ethanol, i.e. the worst selectivity was found for the calcined Ni—Al LDH without hydrothermal treatment.


RSC Advances ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 2284-2291 ◽  
Author(s):  
Jianyao Zhu ◽  
Zhiliang Zhu ◽  
Hua Zhang ◽  
Hongtao Lu ◽  
Yanling Qiu

MgCuFe-layered double hydroxide exhibited high catalytic activity to activate peroxymonosulfate for degradation of organic pollutants. SO4˙− and ·OH are the main reactive radicals involved in the degradation of organic pollutants.


RSC Advances ◽  
2015 ◽  
Vol 5 (17) ◽  
pp. 13239-13245 ◽  
Author(s):  
D. A. Islam ◽  
D. Borah ◽  
H. Acharya

Monodisperse silver nanoparticles supported layered double hydroxides (Ag NPs–LDH) were preferentially deposited on the outer surfaces of pillared LDH offered a high catalytic activity on alcohol oxidation.


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