Applications and Extensions of Statistical Theories
Keyword(s):
The RRKM rate constant as given by equation (6.73) in the previous chapter is expressed as a ratio of the sum of states in the transition state and the density of states in the reactant molecule. An accurate calculation of this rate constant requires that all vibrational anharmonicity and vibrational/rotational coupling be included in calculating the sum and density.
2001 ◽
Vol 105
(11)
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pp. 2453-2457
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2020 ◽
Vol 124
(4)
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pp. 2273-2288
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1987 ◽
Vol 109
(10)
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pp. 2916-2922
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1990 ◽
Vol 112
(9)
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pp. 3338-3347
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1971 ◽
Vol 54
(12)
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pp. 5444-5445
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Keyword(s):
2001 ◽
Vol 115
(18)
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pp. 8460-8480
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