Solar Cells, Thermophotovoltaics, and Nonlinear Devices Based on Quantum Wells
This chapter describes the basic principles behind the solar-cell operation using both an empirical picture and fundamental thermodynamic relationships. It considers how semiconductor materials are selected for use in solar cells and why materials with different gaps need to be stacked to improve the conversion efficiency. It also discusses advanced solar-cell concepts such as quantum-well, intermediate-band, and hot-carrier solar cells. Thermophotovoltaic devices that are similar to solar cells, but designed for emission peaks at much lower effective temperatures than the surface of the sun (and narrower gaps), are also discussed, and multistage thermophotovoltaic devices are described in detail. The chapter concludes by presenting the basic nonlinear physics of intersubband transitions in quantum wells, and how to take advantage of these physical principles for second-harmonic generation and difference-frequency mixing. The important application of generating THz emission from mid-IR quantum cascade lasers using difference-frequency mixing is emphasized.