Boltzmann’s Kinetic Theory

Author(s):  
Sauro Succi

Kinetic theory is the branch of statistical physics dealing with the dynamics of non-equilibrium processes and their relaxation to thermodynamic equilibrium. Established by Ludwig Boltzmann (1844–1906) in 1872, his eponymous equation stands as its mathematical cornerstone. Originally developed in the framework of dilute gas systems, the Boltzmann equation has spread its wings across many areas of modern statistical physics, including electron transport in semiconductors, neutron transport, quantum-relativistic fluids in condensed matter and even subnuclear plasmas. In this Chapter, a basic introduction to the Boltzmann equation in the context of classical statistical mechanics shall be provided.

Author(s):  
Olivier Darrigol

This chapter covers Boltzmann’s writings about the Boltzmann equation and the H theorem in the period 1872–1875, through which he succeeded in deriving the irreversible evolution of the distribution of molecular velocities in a dilute gas toward Maxwell’s distribution. Boltzmann also used his equation to improve on Maxwell’s theory of transport phenomena (viscosity, diffusion, and heat conduction). The bulky memoir of 1872 and the eponymous equation probably are Boltzmann’s most famous achievements. Despite the now often obsolete ways of demonstration, despite the lengthiness of the arguments, and despite hidden difficulties in the foundations, Boltzmann there displayed his constructive skills at their best.


1967 ◽  
Vol 20 (3) ◽  
pp. 205 ◽  
Author(s):  
Kallash Kumar

The Chapman-Enskog method of solving the Boltzmann equation is presented in a simpler and more efficient form. For this purpose all the operations involving the usual polynomials are carried out in spherical polar coordinates, and the Racah-Wigner methods of dealing with irreducible tensors are used throughout. The expressions for the collision integral and the associated bracket expressions of kinetic theory are derived in terms of Talmi coefficients, which have been extensively studied in the harmonic oscillator shell model of nuclear physics.


1968 ◽  
Vol 23 (12) ◽  
pp. 1893-1902
Author(s):  
S. Hess ◽  
L. Waldmann

The relaxation coefficients to be discussed are given by collision brackets pertaining to the linearized collision operator of the generalized Boltzmann equation for particles with spin. The order of magnitude of various nondiagonal relaxation coefficients which are of interest for the SENFTLEBEN-BEENAKKER effect is investigated. Those nondiagonal relaxation coefficients which are linear in the nonsphericity parameter ε (ε essentially measures the ratio of the nonspherical and the spherical parts of the interaction potential), as well as some diagonal relaxation coefficients are expressed in terms of generalized Omega-integrals.


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