scholarly journals Malcolm L. H. Green. 16 April 1936 — 24 July 2020

Author(s):  
Robert H. Crabtree

Malcolm Green was a remarkable man—even a short meeting was enough to make this clear. He had that rare charismatic ability to connect personally with those around him, whatever their rank or status. Generous of his time with his current coworkers, he also made sure to provide help, encouragement or advice to his alumni as the need arose during their subsequent careers. Inspired by his lead, an unusually large number of them have become widely known figures in chemistry in the UK and beyond. Malcolm laid out his view on his students on one occasion when a visitor to the lab commented on how quickly a large sum had been raised by his alumni for a lectureship in his name. ‘They must really love you’, he said, to which Malcolm replied with his simple philosophy: ‘If you love them, they will love you.’ Malcolm's infectious passion for science and his imaginative approach led him in many diverse directions during his career. Although his signature field was organometallic chemistry, he made later important contributions in nanomaterials and heterogeneous catalysis. Always interested in the reasons why Nature behaves as it does, he pioneered several new and imaginative methods for interpreting and understanding chemical bonding and reactivity, such as the covalent bond classification scheme or the rules for predicting the regiochemistry of nucleophilic attack on organometallics. He cared deeply about education and was the author of the first textbook devoted to the organometallic chemistry of the transition metals, Organometallic compounds. Volume 2: the transition elements , which originally appeared as early as 1968.

Author(s):  
Daniel R. Slocombe ◽  
Vladimir L. Kuznetsov ◽  
Wojciech Grochala ◽  
Robert J. P. Williams ◽  
Peter P. Edwards

A qualitative account of the occurrence and magnitude of superconductivity in the transition metals is presented, with a primary emphasis on elements of the first row. Correlations of the important parameters of the Bardeen–Cooper–Schrieffer theory of superconductivity are highlighted with respect to the number of d-shell electrons per atom of the transition elements. The relation between the systematics of superconductivity in the transition metals and the periodic table high-lights the importance of short-range or chemical bonding on the remarkable natural phenomenon of superconductivity in the chemical elements. A relationship between superconductivity and lattice instability appears naturally as a balance and competition between localized covalent bonding and so-called broken covalency, which favours d-electron delocalization and superconductivity. In this manner, the systematics of superconductivity and various other physical properties of the transition elements are related and unified.


Catalysts ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 646
Author(s):  
Victorio Cadierno

The use of organometallic compounds in organic chemistry is one of the cornerstones of the modern synthetic methodology for the activation and generation of new bonds in a molecule [...]


Author(s):  
Anand S Burange ◽  
Awais Ahmad ◽  
Rafael Luque

Efforts to bridge the gap between homogeneous and heterogeneous catalysis include the use of surface organometallic chemistry, single atom catalysis and monodispersed metal nanoparticles, among others. In case of metal...


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