Single-atom active sites on metal-organic frameworks
2012 ◽
Vol 468
(2143)
◽
pp. 1985-1999
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Keyword(s):
Single-site heterogeneous catalysis has been recently accepted as a novel branch of heterogeneous catalysis. Catalysts with single-atom active sites (SAHCs) allow the design and fine-tuning of the active moiety, and can potentially combine the advantages of heterogeneous and homogeneous catalysis. This study illustrates how porous metal-organic frameworks (MOFs) can be synthesized with homogeneous distribution of SAHCs. The catalytic potential of MIXMOFs is shown. A short overview of catalysis with mesoporous silica materials is described to demonstrate their importance in SAHC.
2012 ◽
Vol 468
(2143)
◽
pp. 2035-2052
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Keyword(s):
2014 ◽
Vol 1
(10)
◽
pp. 721-734
◽
2020 ◽
Vol 59
(4)
◽
pp. 2450-2457
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Keyword(s):
2017 ◽
Vol 73
(a2)
◽
pp. C1153-C1153