Fine-Tuning the Porosities of the Entangled Isostructural Zn(II)-Based Metal–Organic Frameworks with Active Sites by Introducing Different N-Auxiliary Ligands: Selective Gas Sorption and Efficient CO2 Conversion

2020 ◽  
Vol 59 (4) ◽  
pp. 2450-2457 ◽  
Author(s):  
Jiao Liu ◽  
Ming Hang ◽  
Dan Wu ◽  
Jing Jin ◽  
Jian-Guo Cheng ◽  
...  
Keyword(s):  
Active Sites ◽  
Metal Organic Frameworks ◽  
Fine Tuning ◽  
Co2 Conversion ◽  
Gas Sorption ◽  
Metal Organic

scholarly journals Single-atom active sites on metal-organic frameworks

2012 ◽  
Vol 468 (2143) ◽  
pp. 1985-1999 ◽  
Author(s):  
Marco Ranocchiari ◽  
Christian Lothschütz ◽  
Daniel Grolimund ◽  
Jeroen Anton van Bokhoven
Keyword(s):  
Heterogeneous Catalysis ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Fine Tuning ◽  
Single Atom ◽  
Homogeneous Distribution ◽  
Catalytic Potential ◽  
Metal Organic ◽  
Heterogeneous And Homogeneous Catalysis

Single-site heterogeneous catalysis has been recently accepted as a novel branch of heterogeneous catalysis. Catalysts with single-atom active sites (SAHCs) allow the design and fine-tuning of the active moiety, and can potentially combine the advantages of heterogeneous and homogeneous catalysis. This study illustrates how porous metal-organic frameworks (MOFs) can be synthesized with homogeneous distribution of SAHCs. The catalytic potential of MIXMOFs is shown. A short overview of catalysis with mesoporous silica materials is described to demonstrate their importance in SAHC.

Metal-organic-framework derived hollow manganese nickel selenide spheres confined with nanosheets on nickel foam for hybrid supercapacitors

2021 ◽  
Author(s):  
Bahareh ameri ◽  
Akbar Mohammadi Zardkhoshoui ◽  
Saied Saeed Hosseiny Davarani
Keyword(s):  
Active Sites ◽  
Nickel Foam ◽  
Metal Organic Framework ◽  
High Surface ◽  
Metal Organic Frameworks ◽  
High Surface Area ◽  
Supercapacitive Performance ◽  
Hybrid Supercapacitors ◽  
Porous Networks ◽  
Metal Organic

Metal-organic frameworks (MOFs) derived nanoarchitectures have special features, such as high surface area (SA), abundant active sites, exclusive porous networks, and remarkable supercapacitive performance when compared to traditional nanoarchitectures. Herein,...

A small molecular, a big scissoring effect: sodium dodecyl sulfate working on two-dimensional metal organic frameworks

CrystEngComm ◽  
2021 ◽  
Author(s):  
Qing Luo ◽  
Zhen Ding ◽  
Huamin Sun ◽  
Zhen Cheng ◽  
Naien SHI ◽  
...  
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Sodium Dodecyl ◽  
Advanced Materials ◽  
Controlled Synthesis ◽  
Two Dimensional ◽  
Dodecyl Sulfate ◽  
Metal Organic

Ultrathin two-dimensional (2D) metal-organic framework (MOF) nanosheets are prosperous advanced materials due to their particularly thin thickness and exposed active sites. The difficulty in the controlled synthesis of 2D MOF...

Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal–Organic Frameworks

2016 ◽  
Vol 138 (8) ◽  
pp. 2524-2527 ◽  
Author(s):  
Quan-Guo Zhai ◽  
Xianhui Bu ◽  
Chengyu Mao ◽  
Xiang Zhao ◽  
Pingyun Feng
Keyword(s):  
Metal Organic Frameworks ◽  
Gas Sorption ◽  
Metal Organic

Incorporation of Chromophores into Metal–Organic Frameworks for Boosting CO2 Conversion

2021 ◽  
Author(s):  
Yun-Nan Gong ◽  
Jin-Wang Liu ◽  
Jian-Hua Mei ◽  
Xue-Lian Lin ◽  
Ji-Hua Deng ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Co2 Conversion ◽  
Metal Organic

Tuning the electrochemical and catalytic ORR performance of C60 by its encapsulation in ZIF-8: a solid-state analogue of dilute fullerene solution

2021 ◽  
Vol 5 (20) ◽  
pp. 7654-7665
Author(s):  
Olivia Basu ◽  
Subhabrata Mukhopadhyay ◽  
Avik De ◽  
Anupam Das ◽  
Samar K. Das
Keyword(s):  
Solid State ◽  
Active Sites ◽  
Metal Organic Frameworks ◽  
Electrochemical Activity ◽  
High Density ◽  
Fullerene Solution ◽  
Metal Organic ◽  
Significant Attention

Hassle-free encapsulation of fullerene C60 in ZIF-8 has been performed to preserve the molecularity and solution-like properties of C60 in solid-state. The resulting composite shows efficient heterogeneous electrocatalytic oxygen reduction reaction.

scholarly journals A combined experimental and theoretical study of gas sorption on nanoporous silver triazolato metal–organic frameworks

2014 ◽  
Vol 183 ◽  
pp. 62-68 ◽  
Author(s):  
Guang Yang ◽  
Juan A. Santana ◽  
Milton E. Rivera-Ramos ◽  
Omar García-Ricard ◽  
Jose J. Saavedra-Arias ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Metal Organic Frameworks ◽  
Gas Sorption ◽  
Metal Organic
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