The Dielectric Behavior of Colloidal Particles with an Electric Double-Layer

1932 ◽  
Vol 40 (4) ◽  
pp. 583-591 ◽  
Author(s):  
J. B. Miles ◽  
H. P. Robertson
2008 ◽  
pp. 21-28
Author(s):  
Tatjana Kuljanin ◽  
Ljubinko Levic ◽  
Nevena Misljenovic ◽  
Gordana Koprivica

Electrokinetic potential is an important property of colloidal particles and, regarding the fact that it is a well defined and easily measurable property, it is considered to be a permanent characteristic of a particular colloidal system. In fact, it is a measure of electrokinetic charge that surrounds the colloidal particle in a solution and is in direct proportion with the mobility of particles in an electric field. Gouy-Chapman-Stern-Graham's model of electric double layer was adopted and it was proven experimentally that the addition of Cu++ ions to sugar beet pectin caused a reduction in the negative electrokinetic potential proportional to the increase of Cu++ concentration. Higher Cu++ concentrations increased the proportion of cation specific adsorption (Cu++ and H+) with regard to electrostatic Coulombic forces. Consequently, there is a shift in the shear plane between the fixed and diffuse layers directed towards the diffuse layer, i.e. towards its compression and decrease in the electrokinetic potential or even charge inversion of pectin macromolecules.


Soft Matter ◽  
2018 ◽  
Vol 14 (22) ◽  
pp. 4520-4529 ◽  
Author(s):  
Chunyu Shih ◽  
John J. Molina ◽  
Ryoichi Yamamoto

The field induced anisotropic interactions between like-charged colloidal particles is studied using direct numerical simulations, where the polarization of the electric double layer is explicitly computed under external AC electric fields.


2016 ◽  
Vol 18 (1) ◽  
pp. 234-243 ◽  
Author(s):  
Jun-Sik Sin ◽  
Hak-Chol Pak ◽  
Kwang-Il Kim ◽  
Kuk-Chol Ri ◽  
Dok-Yong Ju ◽  
...  

Non-uniform size effects and orientational ordering of water dipoles influence the relative permittivity and electric potential in suspension.


2014 ◽  
Vol 134 (5) ◽  
pp. 360-361
Author(s):  
Masumi Fukuma ◽  
Takayuki Uchida ◽  
Yukito Fukushima ◽  
Jinichi Ogawa ◽  
Katsumi Yoshino

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