X-ray diffraction and theoretical studies of the high-pressure structures and phase transitions in magnesium fluoride

2001 ◽  
Vol 64 (13) ◽  
Author(s):  
J. Haines ◽  
J. M. Léger ◽  
F. Gorelli ◽  
D. D. Klug ◽  
J. S. Tse ◽  
...  
2000 ◽  
Vol 56 (s1) ◽  
pp. s216-s216
Author(s):  
J. Haines ◽  
J. M. Léger ◽  
F. Gorelli ◽  
D. D. Klug ◽  
J. S. Tse ◽  
...  

2000 ◽  
Vol 33 (2) ◽  
pp. 279-284 ◽  
Author(s):  
J.-E. Jørgensen ◽  
J. Staun Olsen ◽  
L. Gerward

ReO3has been studied at pressures up to 52 GPa by X-ray powder diffraction. The previously observed cubicIm3¯ high-pressure phase was shown to transform to a monoclinic MnF3-related phase at about 3 GPa. All patterns recorded above 12 GPa could be indexed on rhombohedral cells. The compressibility was observed to decrease abruptly at 38 GPa. It is therefore proposed that the oxygen ions are hexagonally close packed above this pressure, giving rise to two rhombohedral phases labelled I and II. The zero-pressure bulk moduliBoof the observed phases were determined and the rhombohedral phase II was found to have an extremely large value of 617 (10) GPa. It was found that ReO3transforms back to thePm3¯mphase found at ambient pressure.


2019 ◽  
Vol 36 (4) ◽  
pp. 046103 ◽  
Author(s):  
Sheng Jiang ◽  
Jing Liu ◽  
Xiao-Dong Li ◽  
Yan-Chun Li ◽  
Shang-Ming He ◽  
...  

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