Light Scattering through the Isotropic-Cholesteric Phase Transition of a Cholesteric Liquid Crystal

1975 ◽  
Vol 34 (20) ◽  
pp. 1259-1262 ◽  
Author(s):  
T. Harada ◽  
P. P. Crooker
Molecules ◽  
2021 ◽  
Vol 26 (19) ◽  
pp. 6055
Author(s):  
Ju-Yong Kim ◽  
Jae-Jin Lee ◽  
Jun-Sung Park ◽  
Yong-Jun Choi ◽  
Suk-Won Choi

In this paper, a simple and powerful method to control the induced handedness of helical nanofilaments (HNFs) is presented. The nanofilaments are formed by achiral bent-core liquid crystal molecules employing a cholesteric liquid crystal field obtained by doping a rod-like nematogen with a chiral dopant. Homochiral helical nanofilaments are formed in the nanophase-separated helical nanofilament/cholesteric phase from a mixture with a cholesteric phase. This cholesteric phase forms at a temperature higher than the temperature at which the helical nanofilament in a bent-core molecule appears. Under such conditions, the cholesteric liquid crystal field acts as a driving force in the nucleation of HNFs, realizing a perfectly homochiral domain consisting of identical helical nanofilament handedness.


2015 ◽  
Vol 40 (7) ◽  
pp. 1262 ◽  
Author(s):  
J. Etxebarria ◽  
J. Ortega ◽  
C. L. Folcia ◽  
G. Sanz-Enguita ◽  
I. Aramburu

1993 ◽  
Vol 1 (1) ◽  
pp. 43 ◽  
Author(s):  
Yoshikazu Yabe ◽  
Hisatake Yamada ◽  
Toshihiro Hoshi ◽  
Toshiaki Yoshihara ◽  
Akihiro Mochizuki ◽  
...  

2017 ◽  
Vol 114 (9) ◽  
pp. 2137-2142 ◽  
Author(s):  
Yunfeng Li ◽  
Elisabeth Prince ◽  
Sangho Cho ◽  
Alinaghi Salari ◽  
Youssef Mosaddeghian Golestani ◽  
...  

An important goal of the modern soft matter science is to discover new self-assembly modalities to precisely control the placement of small particles in space. Spatial inhomogeneity of liquid crystals offers the capability to organize colloids in certain regions such as the cores of the topological defects. Here we report two self-assembly modes of nanoparticles in linear defects-disclinations in a lyotropic colloidal cholesteric liquid crystal: a continuous helicoidal thread and a periodic array of discrete beads. The beads form one-dimensional arrays with a periodicity that matches half a pitch of the cholesteric phase. The periodic assembly is governed by the anisotropic surface tension and elasticity at the interface of beads with the liquid crystal. This mode of self-assembly of nanoparticles in disclinations expands our ability to use topological defects in liquid crystals as templates for the organization of nanocolloids.


2014 ◽  
Vol 1698 ◽  
Author(s):  
Thomas M. Cooper ◽  
Aaron R. Burke ◽  
Douglas M. Krein ◽  
Ronald F. Ziolo ◽  
Eduardo Arias ◽  
...  

ABSTRACTTo prepare cholesteric liquid crystalline nonlinear optical materials with ability to be vitrified on cooling and form long time stability cholesteric glasses at room temperature, a series of platinum acetylide complexes modified with cholesterol has been synthesized. The materials synthesized have the formula trans-Pt(PR3)(cholesterol (3 or 4)-ethynyl benzoate)(1-ethynyl-4-X-benzene), where R = Et, Bu or Oct and X = H, F, OCH3 and CN. A cholesteric liquid crystal phase was observed in the complexes R = Et, and X = F, OCH3 and CN but not in any of the other complexes. When X = CN, a cholesteric glass was observed at room temperature which remained stable up to 130 °C, then converted to a mixed crystalline/cholesteric phase and completely melted to an isotropic phase at 230 °C. When X = F or OCH3 the complexes were crystalline at room temperature with conversion to the cholesteric phase upon heating to 190 and 230 °C, respectively. In the series X = CN, OCH3 and F, the cholesteric pitch was determined to be 1.7, 3.4 and 9.0 µ, respectively.


Sign in / Sign up

Export Citation Format

Share Document