The angular momentum of an isotropic cholesteric liquid crystal induced by a plane elliptically polarized wave near the phase transition temperature

2019 ◽  
Vol 16 (9) ◽  
pp. 095501 ◽  
Author(s):  
V A Makarov ◽  
V M Petnikova
2011 ◽  
Vol 1312 ◽  
Author(s):  
Ching-Mao Wu ◽  
Szu-Yin Lin ◽  
Kuo-Tung Huang

ABSTRACTThermo-responsive actuation (thermomechanical effects) based on nematic liquid crystal elastomers (LCEs) have become a research priority in the preparation of soft actuators. Nematic LCEs combine the anisotropic features of liquid crystal phases with the rubber elasticity of polymer network. When heated at nematic to isotropic phase transition temperature (N-to-I temp.), a uniaxial thermomechanical deformation of LCEs will undergo at nearly constant volume due to a change of LC director order. Recently, an array of the micro-sized LCE pillars related to such thermomechanical effects have been successfully constructed through a soft lithography technology (i.e., replica molding). The prepared LCE pillars are mono-dispersive and micro-sized. They also possess N-to-I temp. higher than 100°C, largely limiting the available application. By contrast, the present study will report a hexagonal array of nano-sized thermo-responsive pillar actuators that are able to contract and expand in response to temperature changes around a lower N-to-I temp. is manufactured via using reactive rod-like liquid crystal and ultraviolet nanoimprinting technology. According to atomic force microscope (AFM) observation, a hexagonal array of pillars can be easily constructed by nanoimprinting and a responsive surface with a thermo-stimuli-driven roughness change is achieved. The room-temperature AFM scans quantitatively represent the single pillar shows a diameter of ca. 270 nm and 140 nm in depth, and the pitch meaning the averaged inter-pillar distance is measured as ca. 425 nm, thus lying in a nano-sized range. Furthermore, temperature-variable AFM is also utilized to demonstrate the pillar behaves as a thermally-stimulated nano-sized actuator. In our case, when heated above N-to-I phase transition temperature (ca. 65°C), it is clearly observed that the pillar diameter is expanded in the order of over 12-15 % and then reversibly contracted in response to temperature drop.


1999 ◽  
Vol 559 ◽  
Author(s):  
Shin-Tson Wu ◽  
Robert N. Schwartz ◽  
Qing T. Zhang ◽  
Seth Marder ◽  
Chain-Shu Hsu

ABSTRACTSeveral colorless compounds with dielectric anisotropy in the 10-50 range were studied. The absorption spectra, phase transition temperature, birefringence, dielectric anisotropy and visco-elastic coefficient of these compounds were measured.


2010 ◽  
Vol 283 (18) ◽  
pp. 3516-3519 ◽  
Author(s):  
Chia-Chi Shih ◽  
Yu-Jen Chen ◽  
Wen-Chi Hung ◽  
I-Min Jiang ◽  
Ming-Shan Tsai

Author(s):  
A. Minori ◽  
S. Jadhav ◽  
Q. He ◽  
S. Cai ◽  
M. T. Tolley

Recent work has used self-folding origami inspired composites to produce complex, scalable, affordable, and lightweight morphing structures [1]. These characteristics are of interest for engineering applications, in fields including aerospace [2] and medical devices [3]. Due to these advantages, research on self-folding smart composites has grown, with a particular focus on the use of laminate manufacturing techniques that stack layers of heterogeneous materials to generate functional composites. Previous work used this approach to manufacture self-folding origami inspired robots [1]. A simple shape memory composite design consists of a smart material (e.g. a one-way shape memory polymer, or SMP) sandwiched between patterned rigid layers. These SMPs change their shape in response to an external stimulus (e.g. temperature). Upon heating above the phase transition temperature of the polymer (Tt), the SMP contracts, causing the laminate to fold. The SMPs used in self-folding laminate composites are unidirectional and thus the laminate is unable to recover its original state without application of external force. In this work, we study the use of thermal responsive liquid crystal elastomers (LCE) for reversible self-folding and actuation of origami inspired composites using laminate manufacturing. LCEs are smart materials that exhibit reversible deformation, good strain recoverability, and tailorable properties (i.e. phase transition temperature, strain, and orientation of deformation) [4–6]. We explore two composite hinge designs using laminate manufacturing process [1, 7] with a Joule heating layer to enable self-folding: one where the LCE acts as a tensile actuator connected only on the edges of the rigid layer, which we call a tensional hinge, and a second where the LCE is attached along the patterned rigid layer hinge, which we call a flexural hinge. The angular displacements of these two hinge designs are estimated using geometric models that account for the contraction of the LCE upon heating, and compared against experimental measurements. The maximum blocked torque of the composite hinges is also measured experimentally. To demonstrate the use of LCE as an active layer for origami inspired composites, we also present a laminate crawler robot. The crawling locomotion is controlled with an electrical heating layer laminated on the LCE. These results demonstrate the possibility of using LCE to achieve rapid, reversible folding and to generate similar torques, as compared to previous work in origami inspired self-folding composite.


2005 ◽  
Vol 60 (11-12) ◽  
pp. 831-836
Author(s):  
Ivo Grabchev ◽  
Seher Sali

The free radical copolymerisation of five fluorescent 4-allylamino-N-phenyl-substituted 1,8-naphthalimide dyes (MDs) with methylmethacrylate (MMA) has been investigated. The utility of the copolymers prepared as fluorescent component in polymer/liquid crystal systems has been investigated. The basic photophysical properties of monomeric dyes, poly(MMA-co-MD) and poly(MMAco- MD)/liquid crystal mixtures are discussed. The influence of poly(MMA-co-MD) on the phase transition temperature from the nematic to the isotropic state of poly(MMA-co-MD)/liquid crystal mixtures have also been investigated.


Sign in / Sign up

Export Citation Format

Share Document