Hydrido(prolinato-κ2N,O)tris(trimethylphosphane-κP)iridium(III) hexafluoridophosphate
2014 ◽
Vol 70
(2)
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pp. m73-m74
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The title complex, [Ir(C5H8NO2)H(C3H9P)3]PF6, has two independent anion–cation pairs in the asymmetric unit. The geometry about each IrIIIatom is pseudo-octahedral with a meridional arrangement of the P(CH3)3ligands,N,O-bidentate coordination of prolinate and a hydride ligandtransto the prolinate N atom. The independent IrIIImoieties are joined by N—H...O hydrogen bonds and the N—H...O bonding motif continues throughout the structure, creating an extended chain parallel to thec-axis direction. The methyl groups of one P(CH3)3ligand are rotationally disordered over two sets of sites in a 0.62 (2):0.38 (2) ratio.
2015 ◽
Vol 71
(4)
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pp. 350-353
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2015 ◽
Vol 71
(10)
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pp. o778-o779
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2015 ◽
Vol 71
(12)
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pp. m263-m264
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2014 ◽
Vol 70
(3)
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pp. o301-o302
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2012 ◽
Vol 68
(4)
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pp. o1047-o1047
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2014 ◽
Vol 70
(10)
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pp. o1122-o1123
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