Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ3N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate
2015 ◽
Vol 71
(3)
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pp. 309-311
Keyword(s):
The five-coordinate CuIIatom in the title complex [CuCl2(C16H19N3)]·0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu—Cl distance is 0.2626 (6) Å longer than the basal Cu—Cl distance. Weak C—H...Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.
2012 ◽
Vol 68
(4)
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pp. m508-m508
Keyword(s):
2020 ◽
Vol 76
(11)
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pp. 1771-1774
Keyword(s):
2012 ◽
Vol 68
(4)
◽
pp. m468-m468
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Keyword(s):
2007 ◽
Vol 63
(11)
◽
pp. m2810-m2811
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2012 ◽
Vol 68
(8)
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pp. m1101-m1102
Keyword(s):
2007 ◽
Vol 63
(3)
◽
pp. m685-m686
2015 ◽
Vol 71
(11)
◽
pp. m205-m206
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Bis{μ4-N-[phenyl(pyridin-2-ylazanidyl)methyl]pyridin-2-aminido}tetrakis(tetrahydrofuran)tetralithium
2013 ◽
Vol 69
(12)
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pp. m683-m683
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Keyword(s):
2016 ◽
Vol 72
(2)
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pp. 164-169
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Keyword(s):