Dichloro[tris(3-methyl-5-phenylpyrazol-1-yl)methane]copper(II) acetonitrile hemisolvate

2007 ◽  
Vol 63 (3) ◽  
pp. m685-m686
Author(s):  
Hong-Shan He ◽  
Seik Weng Ng
Keyword(s):  
Title Complex ◽  
Tripodal Ligand ◽  
Pyramidal Geometry ◽  
Square Pyramidal Geometry

In the title complex, [CuCl2(C31H28N6)]·0.5C2H3N, the Cu2+ atom is coordinated in a distorted square-pyramidal geometry by three N atoms from the pyrazolyl groups of the tripodal ligand, and by two chloride anions.

scholarly journals (Ethanolato-κO)[N′-(3-methoxy-2-oxidobenzylidene-κO2)benzohydrazidato-κ2N′,O]oxidovanadium(V)

2012 ◽  
Vol 68 (8) ◽  
pp. m1101-m1102
Author(s):  
Xiao-Hua Chen ◽  
Qiong-Jie Wu ◽  
Li-Juan Chen ◽  
Ming-Xing Yang
Keyword(s):  
Hydrogen Bond ◽  
Hydrogen Bonding ◽  
Basal Plane ◽  
Title Complex ◽  
Pyramidal Geometry ◽  
Square Pyramidal Geometry

In the title complex, [V(C15H12N2O4)(C2H5O)O], the VVion is coordinated by an oxide O atom, an ethanolate anion and two O atoms and one N atom from the tridentate benzohydrazidate dianion in a distorted square-pyramidal geometry; the V atom is displaced by 0.4748 (8) Å from the basal plane towards the axial oxide O atom. An intramolecular O—H...N hydrogen bond occurs in the benzohydrazidate ligand. Weak intermolecular C—H...O hydrogen bonding is present in the crystal.

[Bis(2-pyridylmethyl)amine]dichloridozinc(II) chloroform solvate

2007 ◽  
Vol 63 (11) ◽  
pp. m2810-m2811 ◽  
Author(s):  
Young-Inn Kim ◽  
You-Soon Lee ◽  
Hoe-Joo Seo ◽  
Jin-Young Lee ◽  
Sung Kwon Kang
Keyword(s):  
Hydrogen Bonding ◽  
Title Complex ◽  
Pyramidal Geometry ◽  
Hydrogen Bonding Interactions ◽  
Square Pyramidal Geometry ◽  
Cl Atoms ◽  
Centrosymmetric Dimers

The Zn atom in the title complex, [ZnCl2(C12H13N3)]·CHCl3, adopts a distorted square-pyramidal geometry, being coordinated by three N atoms of the tridentate dipicolylamine ligand and two Cl atoms. Intermolecular N—H...Cl hydrogen-bonding interactions link the molecules into centrosymmetric dimers.

scholarly journals Bis{μ4-N-[phenyl(pyridin-2-ylazanidyl)methyl]pyridin-2-aminido}tetrakis(tetrahydrofuran)tetralithium

2013 ◽  
Vol 69 (12) ◽  
pp. m683-m683 ◽  
Author(s):  
Juan Chen
Keyword(s):  
Complex Molecule ◽  
Title Complex ◽  
Coordination Modes ◽  
Bond Lengths ◽  
Pyramidal Geometry ◽  
Metal Atoms ◽  
Square Pyramidal Geometry

The title complex, [Li4(C17H14N4)2(C4H8O)4], bears a novel tetradentate diamido ligand. In the tetranuclear centrosymmetric complex molecule, the metal atoms exhibit two kinds of coordination modes. The middle two Li+cations are coordinated by four N (ligand) and one O (tetrahydrofuran, THF) atoms, resulting in a distorted square-pyramidal geometry. The outer two Li+cations are in distorted tetrahedral environments consisting of three N (ligand) and one O (THF) atoms. The Li—N bond lengths vary from 2.020 (7) to 2.441 (6)Å.

(Benzoylacetonato)chloro[3-(dimethylamino)propylamine]copper(II)

2006 ◽  
Vol 62 (4) ◽  
pp. m843-m845
Author(s):  
Juan-Lan Huang ◽  
Yun-Long Feng
Keyword(s):  
Molecular Structure ◽  
Basal Plane ◽  
Title Complex ◽  
Apical Position ◽  
Pyramidal Geometry ◽  
Square Pyramidal Geometry ◽  
Cl Atom

In the molecular structure of the title complex, [Cu(C10H9O2)Cl(C5H14N2)], the CuII atom is in a distorted square-pyramidal geometry, coordinated by two O atoms of a benzoylacetonate ligand and two N atoms of a 3-(dimethylamino)propylamine ligand in the basal plane, while a Cl atom occupies the apical position.

scholarly journals Crystal structure of (pyridine-κN)bis(quinolin-2-olato-κ2N,O)copper(II) monohydrate

2015 ◽  
Vol 71 (2) ◽  
pp. m38-m39
Author(s):  
Benjamin Hawks ◽  
Jingjing Yan ◽  
Prem Basa ◽  
Shawn Burdette
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Water Molecule ◽  
Crystal Lattice ◽  
Copper Complexes ◽  
Title Complex ◽  
Dihedral Angles ◽  
Pyridine Ligand ◽  
Pyramidal Geometry ◽  
Square Pyramidal Geometry

The title complex, [Cu(C9H6NO)2(C5H4N)]·H2O, adopts a slightly distorted square-pyramidal geometry in which the axial pyridine ligand exhibits a long Cu—N bond of 2.305 (3) Å. The pyridine ligand forms dihedral angles of 79.5 (5) and 88.0 (1)° with the planes of the two quinolin-2-olate ligands, while the dihedral angle between the quinoline groups of 9.0 (3)° indicates near planarity. The water molecule connects adjacent copper complexes through O—H...O hydrogen bonds to phenolate O atoms, forming a network interconnecting all the complexes in the crystal lattice.

scholarly journals (2,2′-Bipyridine-κ2 N,N′){N-[(2-oxidonaphthalen-1-yl-κO)methylidene]-L-valinato-κO}copper(II) trihydrate

2012 ◽  
Vol 68 (6) ◽  
pp. m792-m792 ◽  
Author(s):  
Jian Zuo ◽  
Caifeng Bi ◽  
Yuhua Fan ◽  
Nan Zhang ◽  
Pengfei Zhang
Keyword(s):  
Schiff Base ◽  
Hydrogen Bonds ◽  
Schiff Base Ligand ◽  
Title Complex ◽  
Two Dimensional ◽  
Pyramidal Geometry ◽  
Dimensional Network ◽  
Bipyridine Ligand ◽  
Square Pyramidal Geometry

In the title complex, [Cu(C16H15NO3)(C10H8N2)]·3H2O, the CuII atom is five coordinated by O,N,O′-donor atoms of the Schiff base ligand and by two N atoms of the 2,2′-bipyridine ligand in a distorted square-pyramidal geometry. In the crystal, molecules are linked into a two-dimensional network parallel to (011) by O—H...O hydrogen bonds.

scholarly journals Crystal structure and Hirshfeld surface analysis of (aqua-κO)(methanol-κO)[N-(2-oxidobenzylidene)threoninato-κ3 O,N,O′]copper(II)

2020 ◽  
Vol 76 (9) ◽  
pp. 1539-1542
Author(s):  
Natsuki Katsuumi ◽  
Yuika Onami ◽  
Sayantan Pradhan ◽  
Tomoyuki Haraguchi ◽  
Takashiro Akitsu
Keyword(s):  
Crystal Structure ◽  
Water Molecule ◽  
Surface Analysis ◽  
Complex Molecule ◽  
Hirshfeld Surface ◽  
Title Complex ◽  
Hirshfeld Surface Analysis ◽  
Tridentate Ligand ◽  
Pyramidal Geometry ◽  
Square Pyramidal Geometry

In the title complex molecule, [Cu(C11H11NO4)(CH4O)(H2O)], the Cu atom is coordinated in a distorted square-pyramidal geometry by a tridentate ligand synthesized from L-threonine and salicylaldehyde, one methanol molecule and one water molecule. In the crystal, the molecules show intra- and intermolecular O—H...O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are H...H (49.4%) and H...O/O...H (31.3%) contacts.

scholarly journals Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN 3)imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN 3))copper(II) perchlorate

2019 ◽  
Vol 75 (5) ◽  
pp. 547-551
Author(s):  
Diego da Silva Padilha ◽  
Marciela Scarpellini
Keyword(s):  
Crystal Structure ◽  
Intermolecular Interactions ◽  
Title Complex ◽  
Stacking Interactions ◽  
Metal Centre ◽  
Pyramidal Geometry ◽  
Π Stacking ◽  
Methyl Imidazole ◽  
Square Pyramidal Geometry

In the crystal structure of the title complex, [CuCl(C17H24N8)]ClO4, the copper(II) metal exhibits an N4Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Intermolecular interactions take place at two of the 1-methyl-imidazole rings in the form of parallel-displaced π–π stacking interactions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5.

[N,N,N′-Tris(3-aminopropyl)ethylenediamine-κ5 N]nickel bis(perchlorate)

2006 ◽  
Vol 62 (7) ◽  
pp. m1713-m1715
Author(s):  
Tong-Tao Xu ◽  
Xing-You Xu ◽  
Da-Qi Wang ◽  
Jian Gao ◽  
Lu-De Lu
Keyword(s):  
Hydrogen Bonds ◽  
Network Structure ◽  
Three Dimensional ◽  
Title Complex ◽  
Asymmetric Unit ◽  
Intermolecular Hydrogen Bonds ◽  
Apical Position ◽  
Pyramidal Geometry ◽  
Dimensional Network ◽  
Square Pyramidal Geometry

The asymmetric unit of the title complex, [Ni(C11H29N5)](ClO4)2, consists of an [Ni(C11H29N5)]2+ cation and two uncoordinated perchlorate anions. The NiII atom is five-coordinated in a slightly distorted square-pyramidal geometry, with four of the N atoms forming the basal plane and the fifth N atom in the apical position. The complex shows a three-dimensional network structure assembled by intermolecular hydrogen bonds.

scholarly journals Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ3N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate

2015 ◽  
Vol 71 (3) ◽  
pp. 309-311
Author(s):  
Katherine A. Bussey ◽  
Jennifer R. Connell ◽  
Annie R. McGlone ◽  
Margaret E. Mraz ◽  
Kayode D. Oshin ◽  
...  
Keyword(s):  
Rotation Axis ◽  
Solvent Molecule ◽  
Radical Addition ◽  
Title Complex ◽  
Complex Molecules ◽  
Methyl Amine ◽  
Pyramidal Geometry ◽  
Atom Transfer Radical Addition ◽  
Square Pyramidal Geometry ◽  
Cl Atoms

The five-coordinate CuIIatom in the title complex [CuCl2(C16H19N3)]·0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu—Cl distance is 0.2626 (6) Å longer than the basal Cu—Cl distance. Weak C—H...Cl interactions between pyridine rings and the Cl atoms of adjacent complex molecules are present. The solvent molecule, located on a twofold rotation axis, is situated in the voids of this arrangement. Copper atoms coordinated by tridentate nitrogen-containing ligands have been found to be excellent promoters of Atom Transfer Radical Addition (ATRA) reactions.

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