Crystal structure of {2,6-bis[(dimethylamino)methyl]phenyl-κ3N,C1,N′}(bromido/chlorido)mercury(II)
2017 ◽
Vol 73
(11)
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pp. 1679-1682
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In the molecular structure of the title compound, {2,6-bis[(dimethylamino)methyl]phenyl-κ3N,C1,N′}[bromido/chlorido(0.30/0.70)]mercury(II)–{2,6-bis[(dimethylamino)methyl]phenyl-κ3N,C1,N′}[bromido/chlorido(0.24/0.76)]mercury(II) (1/1), [HgBr0.30Cl0.70(C12H19N2)]·[HgBr0.24Cl0.76(C12H19N2)], there are two molecules in the asymmetric unit of formulaLHgX{L= 2,6-bis[(dimethylamino)methyl]phenyl andX= Cl/Br}. In each molecule, the halide site is mixed Cl/Br, with occupancies of 0.699 (7):0.301 (7) and 0.763 (7):0.237 (7), respectively. The two molecules are linked into dimers by a combination of Hg...Hg [Hg...Hg = 3.6153 (3) Å] and C—H...Cl and C—H...π interactions.
2006 ◽
Vol 62
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pp. m1569-m1571
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pp. 322-324
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2020 ◽
Vol 76
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pp. 1525-1527
2015 ◽
Vol 71
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pp. o504-o505
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2015 ◽
Vol 71
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pp. o210-o211
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2015 ◽
Vol 71
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pp. o123-o124
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2015 ◽
Vol 71
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pp. o143-o144
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2006 ◽
Vol 62
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pp. o2714-o2716
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