Structure of tetrakis(μ-decanoato-κ2
O:O′)bis[(4-methylpyridine-κN)copper(II)], a dimeric copper(II) complex
2020 ◽
Vol 76
(11)
◽
pp. 1775-1778
Keyword(s):
The 4-methylpyridine (4-Mepy) based dimeric copper(II) carboxylate complex [Cu2(C10H19O2)4(C6H7N)2] or [Cu2(μ-O2CC9H19)4(4-Mepy)2] crystallizes with triclinic (P\overline{1}) symmetry. The two CuII ions exhibit a distorted square-pyramidal environment and are connected into a centrosymmetric paddle-wheel dinuclear cluster [Cu...Cu = 2.6472 (8) Å] via four bridging carboxylate ligands arranged in the syn–syn coordination mode. The apical positions around the paddle-wheel copper centers are occupied by the N atoms of the 4-methylpyridine ligands. The structure exhibits disorder of the terminal alkyl carbon atoms in the decanoate chains.
2020 ◽
Vol 76
(2)
◽
pp. 225-230
2009 ◽
Vol 65
(a1)
◽
pp. s307-s307
Keyword(s):
2004 ◽
Vol 7
(2)
◽
pp. 235-237
◽
2018 ◽
Vol 74
(12)
◽
pp. 1641-1649
2013 ◽
Vol 66
(12)
◽
pp. 2166-2177
◽