Bis(μ-4-amino-N-oxidobenzamide)bis[(4-amino-N-oxidobenzamide)aquacobalt] dihydrate
Keyword(s):
The structure of the title compound, [Co2(C7H7N2O2)4(H2O)2]·2H2O, consists of a centrosymmetric binuclear [Co2(4-Apha)4(H2O)2] complex molecule (4-AphaH = 4-aminophenylhydroxamic acid), and two solvent water molecules. Each CoII cation is six coordinate, binding five oxygen atoms from three 4-Apha− ligands and a water molecule in a slightly distorted octahedral geometry. Two of the 4-Apha− ligands bridge two neighbouring CoII ions to form the binuclear complex. A three-dimensional network structure is generated by O—H...O, N—H...O, and N—H...N hydrogen bonds.
2007 ◽
Vol 63
(11)
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pp. m2752-m2752
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2012 ◽
Vol 68
(6)
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pp. m801-m802
2012 ◽
Vol 68
(4)
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pp. m413-m414
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2012 ◽
Vol 68
(8)
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pp. m1088-m1088
2013 ◽
Vol 69
(12)
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pp. m640-m641
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2015 ◽
Vol 71
(9)
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pp. m167-m168
2013 ◽
Vol 69
(2)
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pp. m99-m100
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2012 ◽
Vol 68
(6)
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pp. m761-m762
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2015 ◽
Vol 71
(4)
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pp. 342-345
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2019 ◽
Vol 75
(10)
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pp. 1463-1466