(2R,4S,5S)-5-Methoxy-4-methyl-3-oxohept-6-en-2-yl benzoate
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The title compound, C16H20O4, was synthesized in the course of the total synthesis of fusaequisin A in order to verify and confirm the configurations of the stereogenic centers and to exclude the possibility of epimerization during the methylation process. The crystal structure of the title compound at 100 K has orthorhombic (P212121) symmetry. The absolute configuration was determined by anomalous dispersion and agrees with the configuration of the allylic alcohol used in the synthesis.
2006 ◽
Vol 62
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pp. o1774-o1776
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2007 ◽
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pp. o4196-o4196
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2007 ◽
Vol 63
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pp. o4439-o4439
2015 ◽
Vol 71
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pp. 79-81
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2006 ◽
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pp. o2622-o2624
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2006 ◽
Vol 62
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pp. o3011-o3012
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2015 ◽
Vol 71
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pp. o1055-o1056
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2007 ◽
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pp. o4368-o4369
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2016 ◽
Vol 72
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pp. 1081-1084
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