According to the characteristics of HF channel and chirp signal, an innovative multipath time-delay model of wide-band HF channel was proposed, by which the estimation problem of time-delay was converted into an estimation problem of spectrum.Then the MUSIC algorithm with super-resolution ability was applied to the problem above. The feasibility of estimating multipath time-delays based on single measurement data was deeply discussed. Meanwhile, the performance of applying MUSIC and root MUSIC algorithm to the model proposed in the paper was presented. The simulation results suggested that the method proposed in the paper owned super-resolution ability and robust in estimation of multipath time-delay.