Iterative Learning Control of Methane Steam Reforming Reaction in Operating Solid Oxide Fuel Cell

Author(s):  
Xin Kang ◽  
Yong Chen ◽  
Liyuan Fan ◽  
Deqing Huang
2009 ◽  
Vol 29 (5-6) ◽  
pp. 1106-1113 ◽  
Author(s):  
Yongping Yang ◽  
Xiaoze Du ◽  
Lijun Yang ◽  
Yuan Huang ◽  
Haizhen Xian

2014 ◽  
Vol 2014 ◽  
pp. 1-8 ◽  
Author(s):  
D. Mogensen ◽  
J.-D. Grunwaldt ◽  
P. V. Hendriksen ◽  
J. U. Nielsen ◽  
K. Dam-Johansen

The kinetics of catalytic steam reforming of methane over an Ni-YSZ anode of a solid oxide fuel cell (SOFC) have been investigated with the cell placed in a stack configuration. In order to decrease the degree of conversion, a single cell stack with reduced area was used. Measurements were performed in the temperature range 600–800°C and the partial pressures of all reactants and products were varied. The obtained rates could be well fitted with a power law expression (r ∝PCH40.7). A simple model is presented which is capable of predicting the methane conversion in a stack configuration from intrinsic kinetics of the anode support material. The predictions are compared with the stack measurements presented here, and good agreement is observed.


2020 ◽  
Vol 472 ◽  
pp. 228605
Author(s):  
Tariq Nawaz Chaudhary ◽  
Mubbashar Mehmood ◽  
Umer Saleem ◽  
Muhammad Salman Abbasi ◽  
Baixin Chen

2006 ◽  
Vol 972 ◽  
Author(s):  
Vladislav A Sadykov ◽  
Natalia V Mezentseva ◽  
Rimma v Bunina ◽  
Galina M Alikina ◽  
Anton I Lukashevich ◽  
...  

AbstractEffect of fluorite-like or perovskite-like complex oxide promoters and Pd on the performance of Ni/YSZ and Ni/ScSZ cermets in methane steam reforming or selective oxidation by O2 into syngas at short contact times was studied. Spatial uniformity of dopants distribution in composites was controlled by TEM combined with EDX, while the lattice oxygen mobility and reactivity was elucidated by CH4 and H2 TPR. Oxide promoters allow to operate even at stoichiometric H2O/CH4 ratio by suppressing coke deposition through modification of Ni surface, while doping by Pd ensures reasonable performance at moderate (∼550 °C) temperatures required for Intermediate–Temperature Solid Oxide Fuel Cells (IT SOFC).


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