Electrical properties of fluorinated gel electrolytes using conducting solution and its application to secondary battery

Magnesium-based polymer gel electrolytes consist of magnesium triflate (MgTf) salt, a mixture of ethylene carbonate (EC) and diethyl carbonate (DEC) solvents as well as cellulose acetate as a polymeric agent were prepared via direct dissolution method. The highest ionic conductivity obtained for MgTf-EC:DEC(1: 1) liquid electrolytes was 2. 66 x 10-3 S cm·1 and enhanced to 2.73 x 10-3 S cm·1 with the addition of cellulose acetate. These results were in agreement with the activation energy obtained with the lowest value of 0.11. The best explanation on the enhancement in ionic conductivity of PGE is due to the "breathing polymeric chain model". The plots of conductivity-temperature were shown to obey an Arhenius rule. The electrical properties of the sample with the highest conductivity were analyzed using electrical permittivity-based frequency and temperature dependence in the range of JOO Hz-1 MHz and 303-373K, respectively. The variation in dielectric permittivity (e, and e) as a function of frequency at different temperatures exhibited decays at higher frequencies and a dispersive behavior at low frequencies. Based on the observed electrical properties, it can be inferred that this polymer gel electrolyte could be a promising candidate as an electrolyte in electrochemical devices.

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Ionic Conductivity Studies on Magnesium-Based Cellulose Acetate Polymer Gel Electrolytes

Scientific Research Journal ◽

10.24191/srj.v12i2.5428 ◽

2015 ◽

Vol 12 (2) ◽

pp. 25

Author(s):

Aniza Omar ◽

Siti Zafirah Zainal Abidin ◽

Ainnur Sherene Kamisan ◽

Siti Irma Yuana Sheikh Mohd Saaid ◽

Ab Malik Marwan Afi ◽

...

Keyword(s):

Ionic Conductivity ◽

Electrical Properties ◽

Cellulose Acetate ◽

Ethylene Carbonate ◽

Polymeric Chain ◽

Chain Model ◽

Polymer Gel ◽

Polymer Gel Electrolyte ◽

Gel Electrolytes ◽

Polymer Gel Electrolytes

Magnesium-based polymer gel electrolytes consist of magnesium triflate (MgTf) salt, a mixture of ethylene carbonate (EC) and diethyl carbonate (DEC) solvents as well as cellulose acetate as a polymeric agent were prepared via direct dissolution method. The highest ionic conductivity obtained for MgTf-EC:DEC(1: 1) liquid electrolytes was 2.66 x 10-3 S cm-1 and enhanced to 2.73 x 10-3 S cm-1 with the addition of cellulose acetate. These results were in agreement with the activation energy obtained with the lowest value of 0.11. The best explanation on the enhancement in ionic conductivity of PGE is due to the "breathing polymeric chain model". The plots of conductivity-temperature were shown to obey an Arrhenius rule. The electrical properties of the sample with the highest conductivity were analyzed using electrical permittivity-based frequency and temperature dependence in the range of 100 Hz-1 MHz and 303-373K, respectively. The variation in dielectric permittivity (er and ei) as a function of frequency at different temperatures exhibited decays at higher frequencies and a dispersive behavior at low frequencies. Based on the observed electrical properties, it can be infe"ed that this polymer gel electrolyte could be a promising candidate as an electrolyte in electrochemical devices.

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Enhancement in Electrical Properties of PEO Based Nano-Composite Gel Electrolytes

i-manager s Journal on Material Science ◽

10.26634/jms.2.3.2962 ◽

2014 ◽

Vol 2 (3) ◽

pp. 12-17 ◽

Cited By ~ 5

Author(s):

Rajiv Kumar ◽

Keyword(s):

Electrical Properties ◽

Nano Composite ◽

Gel Electrolytes ◽

Composite Gel

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The synthesis and electrical properties of hybrid gel electrolytes derived from Keggin-type heteropoly acids and 3-(pyridin-1-ium-1-yl)propane-1-sulfonate (PyPs)

RSC Advances ◽

10.1039/c6ra23082b ◽

2016 ◽

Vol 6 (104) ◽

pp. 102549-102556 ◽

Cited By ~ 5

Author(s):

Sumaletha Narayanan ◽

Xia Tong ◽

Venkataraman Thangadurai

Keyword(s):

Electrical Conductivity ◽

Cyclic Voltammetry ◽

Electrical Properties ◽

Room Temperature ◽

Proton Conductors ◽

Heteropoly Acids ◽

Hybrid Gel ◽

Keggin Type ◽

Gel Electrolytes ◽

Scan Rate

Cyclic voltammetry of PyPs–H3PWMo at room temperature between −4 and +4 V vs. Ag/AgCl at a 10 mV s−1 scan rate and comparison of electrical conductivity of PyPs–H3PWMo with other known promising proton conductors.

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In situ TEM measurements of the electrical properties of interface dislocations

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100131322 ◽

1992 ◽

Vol 50 (2) ◽

pp. 1338-1339

Author(s):

F. M. Ross ◽

R. Hull ◽

D. Bahnck ◽

J. C. Bean ◽

L. J. Peticolas ◽

...

Keyword(s):

Electrical Properties ◽

Electronic Device ◽

In Situ Tem ◽

Device Performance ◽

Misfit Dislocations ◽

Electrical Characteristics ◽

Strained Layer ◽

Transmission Electron ◽

Interfacial Dislocations

We describe an investigation of the electrical properties of interfacial dislocations in strained layer heterostructures. We have been measuring both the structural and electrical characteristics of strained layer p-n junction diodes simultaneously in a transmission electron microscope, enabling us to correlate changes in the electrical characteristics of a device with the formation of dislocations.The presence of dislocations within an electronic device is known to degrade the device performance. This degradation is of increasing significance in the design and processing of novel strained layer devices which may require layer thicknesses above the critical thickness (hc), where it is energetically favourable for the layers to relax by the formation of misfit dislocations at the strained interfaces. In order to quantify how device performance is affected when relaxation occurs we have therefore been investigating the electrical properties of dislocations at the p-n junction in Si/GeSi diodes.

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