heteropoly acids
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Fuel ◽  
2021 ◽  
Vol 301 ◽  
pp. 121083
Author(s):  
Reem Ghubayra ◽  
Rana Yahya ◽  
Elena F. Kozhevnikova ◽  
Ivan V. Kozhevnikov

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 988
Author(s):  
Reem Ghubayra ◽  
Rachel Hindle ◽  
Rana Yahya ◽  
Elena F. Kozhevnikova ◽  
Ivan V. Kozhevnikov

Aerobic oxidative desulfurization (ODS) of model liquid fuel (dodecane spiked with dibenzothiophene (DBT)) was carried out in the presence of bulk and supported Keggin-type heteropoly acids H3+nPMo12-nVnO40 (HPA-n, n = 0–3) as heterogeneous catalysts and benzaldehyde as a sacrificial reductant. In the presence of bulk H4PMo11VO40 (HPA-1), 100% of DBT was removed from fuel (converted to DBT sulfone) at 60 °C and ambient air pressure. Multiple catalyst reuse without loss of activity was demonstrated. The ODS reaction was strongly inhibited by radical scavengers. An unbranched radical chain mechanism was proposed.


ACS Omega ◽  
2021 ◽  
Author(s):  
Rawan Al-Faze ◽  
Elena F. Kozhevnikova ◽  
Ivan V. Kozhevnikov

Soft Matter ◽  
2021 ◽  
Author(s):  
Xue Wang ◽  
Xiaohuan Liu ◽  
Zhiyuan Ma ◽  
Chuanling Mu ◽  
Wen Li

A new kind of supramolecular hydrogels have been designed and synthesized via the co-assembly of basic amino acids (AAs) and heteropoly acids (HPAs) under acidic condition. The formation of gel-like...


2021 ◽  
Vol 13 (1) ◽  
pp. 73-80
Author(s):  
N. V. Gromov ◽  
T. B. Medvedeva ◽  
O. P. Taran ◽  
M. N. Timofeeva ◽  
V. N. Parmon

2020 ◽  
Vol 56 (4) ◽  
pp. 2944-2960
Author(s):  
Syun Gohda ◽  
Makoto Saito ◽  
Yasuhiro Yamada ◽  
Shuhei Kanazawa ◽  
Hironobu Ono ◽  
...  
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2020 ◽  
Vol 118 (18) ◽  
pp. e1759832
Author(s):  
Shaoping Hu ◽  
Litong Niu ◽  
Yuli Wei ◽  
Lina Chen ◽  
Zhiwang Yang

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