Identification and quantification of 10 indole/indazole carboxamide synthetic cannabinoids in 36 herbal blends by gas chromatography‐mass spectrometry and nuclear magnetic resonance spectroscopy

2021 ◽  
Author(s):  
Cui‐Mei Liu ◽  
Wei Jia ◽  
Xin Meng ◽  
Zhen‐Dong Hua
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Gas Chromatography ◽  
Magnetic Resonance ◽  
Magnetic Resonance Spectroscopy ◽  
Nuclear Magnetic Resonance Spectroscopy ◽  
Synthetic Cannabinoids ◽  
Gas Chromatography Mass Spectrometry ◽  
Resonance Spectroscopy ◽  
Identification And Quantification

scholarly journals Dihydrotagetone, an Unusual Fruity Ketone, is Found in Enantiopure and Enantioenriched Forms in Additional Australian Native Taxa of Phebalium (Rutaceae: Boronieae)

2013 ◽  
Vol 8 (6) ◽  
pp. 1934578X1300800 ◽  
Author(s):  
Nicholas J. Sadgrove ◽  
Ian R. H. Telford ◽  
Ben W. Greatrex ◽  
Ashley Dowell ◽  
Graham L. Jones
Keyword(s):  
Mass Spectrometry ◽  
Nuclear Magnetic Resonance ◽  
Gas Chromatography ◽  
Magnetic Resonance ◽  
Essential Oil ◽  
Magnetic Resonance Spectroscopy ◽  
Essential Oils ◽  
Gas Chromatography Mass Spectrometry ◽  
Resonance Spectroscopy ◽  
First Time

Here we report for the first time hydrodistillation of leaf essential oils from Phebalium squamulosum subsp. verrucosum, P. glandulosum subsp. eglandulosum, P. glandulosum subsp. nitidum and P. glandulosum subsp. angustifolium (Rutaceae: Boronieae). Essential oils were analysed using gas-chromatography/mass spectrometry (GC-MS) and nuclear magnetic resonance spectroscopy (NMR). With the exception of P. glandulosum subsp. angustifolium, all taxa yielded essential oils in relatively high amounts (1–3%, w/w) made up predominantly of 2,6-dimethyloct-7-en-4-one (dihydrotagetone). The essential oil from P. squamulosum subsp. verrucosum contains either (+)-dihydrotagetone ( ee 94–100%) or (-)-dihydrotagetone ( ee 17–18%). Taxonomically, these results support the proposal that P. squamulosum subsp. verrucosum may be specifically misplaced, phytochemically resembling the P. glandulosum complex. Similarly, P. glandulosum subsp. angustifolium phytochemically resembles P. distans or P. longifolium and also appears to be assigned incorrectly to the P. glandulosum group.

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