scholarly journals Does the pressure dependence of kinetic isotope effects report usefully on dynamics in enzyme H‐transfer reactions?

FEBS Journal ◽  
2015 ◽  
Vol 282 (16) ◽  
pp. 3243-3255 ◽  
Author(s):  
Robin Hoeven ◽  
Derren J. Heyes ◽  
Sam Hay ◽  
Nigel S. Scrutton
Keyword(s):  
Pressure Dependence ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Transfer Reactions ◽  
Kinetic Isotope

Ab initio predictions and experimental confirmation of large tunneling contributions to rate constants and kinetic isotope effects for hydrogen atom transfer reactions

1986 ◽  
Vol 108 (12) ◽  
pp. 3515-3516 ◽  
Author(s):  
Bruce C. Garrett ◽  
Donald G. Truhlar ◽  
Joel M. Bowman ◽  
Albert F. Wagner ◽  
Daniel. Robie ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Ab Initio ◽  
Rate Constants ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Hydrogen Atom Transfer ◽  
Experimental Confirmation ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Kinetic Isotope

Steric Effects on the Primary Isotope Dependence of Secondary Kinetic Isotope Effects in Hydride Transfer Reactions in Solution: Caused by the Isotopically Different Tunneling Ready State Conformations?

2015 ◽  
Vol 137 (20) ◽  
pp. 6653-6661 ◽  
Author(s):  
Binita Maharjan ◽  
Mahdi Raghibi Boroujeni ◽  
Jonathan Lefton ◽  
Ormacinda R. White ◽  
Mortezaali Razzaghi ◽  
...  
Keyword(s):  
Isotope Effects ◽  
Hydride Transfer ◽  
Kinetic Isotope Effects ◽  
Transfer Reactions ◽  
Steric Effects ◽  
Kinetic Isotope ◽  
Hydride Transfer Reactions

ChemInform Abstract: PROTON-TRANSFER REACTIONS. 4. NEAR-UNITY KINETIC ISOTOPE EFFECTS FOR HYDRON EXCHANGE AND DEHYDROFLUORINATION REACTIONS

1983 ◽  
Vol 14 (31) ◽  
Author(s):  
H. F. KOCH ◽  
D. B. DAHLBERG ◽  
G. LODDER ◽  
K. S. ROOT ◽  
N. A. TOUCHETTE ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Transfer Reactions ◽  
Kinetic Isotope ◽  
Proton Transfer Reactions
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