An Experimental Investigation of the Effects of the Environmental Conditions and the Channel Depth for an Air-Breathing Polymer Electrolyte Membrane Fuel Cell

2008 ◽  
Vol 5 (4) ◽  
Author(s):  
Yong Hun Park ◽  
Jerald A. Caton

The effects of the environmental conditions and the channel depth for an air-breathing polymer electrolyte membrane fuel cell were investigated experimentally. The fuel cell used in this work included a membrane and electrode assembly, which possessed an active area of 25 cm2 with Nafion® 117 membrane. Triple serpentine designs for the flow fields with two different flow depths were used in this research. The experimental results indicated that the relative humidity and temperature play an important role with respect to fuel cell performance. The fuel cell needs to be operated at least 20 min to obtain stable performance. When the shallow flow field was used, the performance increased dramatically for low humidity and slightly for high humidity. The current density was obtained around only 120 mA/cm2 at 30°C with an 80% relative humidity, which was nearly double the performance for the deep flow field. The minimum operating temperature for an air-breathing fuel cell would be 20°C. When it was 10°C at 60% relative humidity, the open circuit voltage dropped to around 0.65 V. The fuel cell performance improved with increasing relative humidity from 80% to 100% at high current density.

Author(s):  
M. Wu ◽  
M. C. Leu ◽  
N. Guo

Polymer Electrolyte Membrane (PEM) fuel cell converts directly electrochemical energy into electricity. Flow channels in bipolar plates, a critical component of fuel cell, were designed, simulated and tested. The bipolar plate used a mixture of graphite materials, and was fabricated using a Selective Laser Sintering (SLS) process. The fabricated green parts were carbonized at high temperatures and converted into brown parts. Infiltration of resin was used to enhance the electric conductivity and strength of the bipolar plate. Finite element simulations were performed to investigate the state of species (hydrogen, oxygen) in the channels and Gas Diffusion Layers (GDLs) for four flow field designs including parallel, serpentine, single Hilbert and composite Hilbert. The simulation results were used to obtain the polarization curves and the relationships between stack power and current density, and to discuss the effect of temperature on fuel cell performance. Experiments were conducted to validate the simulation results on voltage and power vs. current density and the effect of temperature on fuel cell performance for the different flow field designs.


Polymers ◽  
2020 ◽  
Vol 12 (6) ◽  
pp. 1354 ◽  
Author(s):  
Je-Deok Kim ◽  
Satoshi Matsushita ◽  
Kenji Tamura

A crosslinked sulfonated polyphenylsulfone (CSPPSU) polymer and polyvinyl alcohol (PVA) were thermally crosslinked; then, a CSPPSU-vinylon membrane was synthesized using a formalization reaction. Its use as an electrolyte membrane for fuel cells was investigated. PVA was synthesized from polyvinyl acetate (PVAc), using a saponification reaction. The CSPPSU-vinylon membrane was synthesized by the addition of PVA (5 wt%, 10 wt%, 20 wt%), and its chemical, mechanical, conductivity, and fuel cell properties were studied. The conductivity of the CSPPSU-10vinylon membrane is higher than that of the CSPPSU membrane, and a conductivity of 66 mS/cm was obtained at 120 °C and 90% RH (relative humidity). From a fuel cell evaluation at 80 °C, the CSPPSU-10vinylon membrane has a higher current density than CSPPSU and Nafion212 membranes, in both high (100% RH) and low humidification (60% RH). By using a CSPPSU-vinylon membrane instead of a CSPPSU membrane, the conductivity and fuel cell performance improved.


2013 ◽  
Vol 11 (1) ◽  
Author(s):  
Nannan Guo ◽  
Ming C. Leu

Selective laser sintering (SLS) was used to fabricate graphite composite plates for polymer electrolyte membrane fuel cells, which has the advantages of reducing time and cost associated with the research and development of bipolar plates. Graphite composite plates with three different designs, i.e., parallel in series, interdigitated, and bio-inspired, were fabricated using the SLS process. The performance of these SLS fabricated plates was studied experimentally within a fuel cell assembly under various operating conditions. The effect of temperature, relative humidity, and pressure on fuel cell performance was investigated. In the tests conducted in this study, the best fuel cell performance was achieved with a temperature of 65–75°C, relative humidity of 100%, and back pressure of 2 atm. The performance of fuel cell operating over an extended time was also studied, with the result showing that the SLS fabricated graphite composite plates provided a relatively steady fuel cell output power.


2014 ◽  
Vol 4 (5) ◽  
pp. 1400-1406 ◽  
Author(s):  
Yuta Nabae ◽  
Mayu Sonoda ◽  
Chiharu Yamauchi ◽  
Yo Hosaka ◽  
Ayano Isoda ◽  
...  

A Pt-free cathode catalyst for polymer electrolyte membrane fuel cells has been developed by multi-step pyrolysis of Fe phthalocyanine and phenolic resin and shows a quite promising fuel cell performance.


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