Overview of Direct Carbonate Fuel Cell Technology and Products Development

Author(s):  
Hossein Ghezel-Ayagh ◽  
Anthony J. Leo ◽  
Hans Maru ◽  
Mohammad Farooque

Significant progress has been made in development of power generation products based on carbonate fuel cells. Carbonate fuel cell systems provide high efficiency and ultra-clean power generation from a variety of gaseous, liquid, and solid carbonaceous fuels. The high operating temperature of 650 °C in carbonate fuel cell allows significant system simplification by integrating the internal reforming feature into the fuel cell stack as well as use of the byproduct heat in an efficient bottoming cycle. Direct FuelCell® (DFC®) is a unique version of the carbonate fuel cell, which generates electricity directly from a hydrocarbon fuel by reforming the fuel inside the fuel cell and producing hydrogen. The direct reforming concept eliminates the need for an external reformer resulting in power plants with reduced capital cost. This feature also allows the DFC power plants to utilize the existing fuel distribution infrastructure. The first generation of products offered by FuelCell Energy (FCE) range from 250kW to 2MW and is suitable to operate on natural gas, digester gas and other fuels. Presently, a fleet of natural gas fueled units is operating in the US and Europe at customers’ sites. Additionally, there are subsequent power plants planned to operate on a variety of fuels, including coal-bed methane, digester gas, and coal-derived gas. A 2 MW fuel cell power plant (DFC3000) will soon be operating with coal gas in Wabash River, Indiana’s coal gasification plant. The field tests of a 1 MW unit (DFC1500) at King County (Seattle, WA) waste treatment will be demonstrating the unique features of the DFC technology with digester gas as a fuel. There are plans to operate a 250 kW (DFC300) unit on coal-bed methane fields in Cadiz, Ohio. FCE is also developing a 500 kW unit for the US NAVY, operating on marine distillate fuels. FCE is also developing fuel cell/turbine ultra-high efficiency hybrid power plants with efficiencies approaching 75%. In the Direct FuelCell/Turbine® (DFC/T®) power cycle, the fuel cell is integrated with an indirectly heated gas turbine. FCE has recently completed the operation of a ‘proof-of-concept’ system that combined a sub-megawatt DFC with a 30-kilowatt microturbine. The proof-of-concept tests demonstrated that the DFC/T hybrid concept, indeed, has the potential for achieving higher efficiencies than the single cycle fuel cell. The demonstration of two, packaged sub-megawatt DFC/T units, one in Danbury and one at a customer site in Montana, is planned. In addition to pioneering the Direct FuelCell technology, FCE has established a strong manufacturing base. Currently the manufacturing facility at Torrington, CT, has the equipment in place to produce 50 MW per year of fuel cells. FCE has also established commercial distribution alliances with electric power equipment sales and service companies, energy service and solution providers, and specialty application developers for marketing DFC products. The operation of FCE’s power plants at customer sites, continuing efforts in technology improvement, and the favorable reception of the customers for DFC-based units, combined with a network of partners for sales and services, are the key factors for market penetration of DFC products.

Author(s):  
Vikram Muralidharan ◽  
Matthieu Vierling

Power generation in south Asia has witnessed a steep fall due to the shortage of natural gas supplies for power plants and poor water storage in reservoirs for low hydro power generation. Due to the current economic scenario, there is worldwide pressure to secure and make more gas and oil available to support global power needs. With constrained fuel sources and increasing environmental focus, the quest for higher efficiency would be imminent. Natural gas combined cycle plants operate at a very high efficiency, increasing the demand for gas. At the same time, countries may continue to look for alternate fuels such as coal and liquid fuels, including crude and residual oil, to increase energy stability and security. In over the past few decades, the technology for refining crude oil has gone through a significant transformation. With the advanced refining process, there are additional lighter distillates produced from crude that could significantly change the quality of residual oil used for producing heavy fuel. Using poor quality residual fuel in a gas turbine to generate power could have many challenges with regards to availability and efficiency of a gas turbine. The fuel needs to be treated prior to combustion and needs a frequent turbine cleaning to recover the lost performance due to fouling. This paper will discuss GE’s recently developed gas turbine features, including automatic water wash, smart cooldown and model based control (MBC) firing temperature control. These features could significantly increase availability and improve the average performance of heavy fuel oil (HFO). The duration of the gas turbine offline water wash sequence and the rate of output degradation due to fouling can be considerably reduced.


Author(s):  
Zhiwen Ma ◽  
Ramakrishnan Venkataraman ◽  
Mohammad Farooque

Fuel cell power generation has evolved from the laboratory and aerospace applications, and moved onto practical applications of stationary power generation and automotive propulsion, driven by its high-energy efficiency and low emissions. The success of the fuel cell technology depends on its performance, cost, and reliability in commercial applications. Fuel Cell Energy Inc. (Danbury, CT) has been developing its direct fuel cell (DFC™) technology for power generation based on internal-reforming carbonate fuel cells. The DFC technology integrates the reforming reaction within the carbonate fuel cell stack. The integration of the reforming process inside the high temperature fuel cell stack simplifies the fuel cell power plant system and makes the fuel cell technology more accessible to the practical usage with low cost and high efficiency. The internal-reforming direct carbonate fuel cell technology has progressed steadily with improvement in performance and success in precommercialization applications. Modeling and simulation of the fuel cell performance played an important role in the fuel cell development. This paper will illustrate improved mathematical model for the direct carbonate fuel cell with the internal-reforming process and complete fuel cell physical and chemical descriptions for the simulation. The model has been validated with data from real-scale fuel cell stacks and applied to fuel cell stack design. More powerful and reliable DFC stack with improved performance has been developed with the assistance of this model. This paper will present progress in developing high performance stack designs aided by modeling efforts, its impact on power increase, and cost reduction in the DFC product.


Author(s):  
Joseph McInerney ◽  
Hossein Ghezel-Ayagh ◽  
Robert Sanderson ◽  
Jennifer Hunt

High temperature fuel cells, such as Molten Carbonate Fuel Cells (MCFC), are prime candidates for power generation using natural gas. Currently MCFC-based products are available for on-site power generation using natural gas and methane-rich biogas. These systems use the most advanced stack configuration utilizing internal reforming of methane. The in-situ reforming within the fuel cell anode provides many operational benefits including stack cooling at high current densities. Syngas from a variety of sources such as coal, biomass and renewables are anticipated to play a key role in the future landscape of power generation. MCFC is capable of utilizing syngss to produce electric power at a very high efficiency. However, because of the differences in the gas compositions between natural-gas and syngas, the fuel cell stack and system designs need to be modified for syngas fuels. The purpose of this study is to develop the design modifications at both the stack and system level needed for operation of internal reforming MCFC using low-methane content syngas without major design changes from the commercial product design. The net outcome of the investigation is a fuel cell system which meets the goals of being able to operate on low methane syngas within thermo-mechanical requirements of the fuel cell stack components. In this paper, we will describe the approach for modification of MCFC design and operating parameters for operation under syngas using both system level modeling and stack level mathematical modeling.


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