Advances in Electrochemical Compression of Hydrogen

Author(s):  
Jennie M. Moton ◽  
Brian D. James ◽  
Whitney G. Colella

This paper evaluates the potential for electrochemical hydrogen compression systems (EHCs) regarding their engineering performance, manufacturability, and capital costs. EHCs could enhance or replace mechanical hydrogen compressors. The physical embodiment of EHCs is similar to that of low temperature (LT) proton exchange membrane (PEM) fuel cell systems (FCSs). They also share common operating principles with LT PEM FCS and with PEM electrolysis systems. Design for Manufacturing and Assembly (DFMA™) analysis is applied to EHCs to identify manufactured designs, manufacturing methods, projected capital costs under mass-production, and cost drivers for both the EHC stack and the balance of plant (BOP). DFMA™ analysis reveals that EHC stack costs are expected to be roughly equal to EHC BOP costs, under a variety of scenarios. (Total EHC system costs are the sum of stack and BOP costs.) Within the BOP, the primary cost driver is the electrical power supply. Within the stack, the primary cost drivers include the membrane electrode assembly (MEA), the stamped bipolar plates, and the expanded titanium (Ti) cell supports, particularly at lower hydrogen outlet pressures. As outlet pressure rises, capital costs escalate nonlinearly for several reasons. Higher pressure EHCs experience higher mechanical loads, which necessitate using a greater number of smaller diameter cells and a greater tie rod mass. Higher pressure EHCs also exhibit a higher degree of back-diffusion, which necessitates using more cells per system.

Author(s):  
Britta Mayerhöfer ◽  
Konrad Ehelebe ◽  
Florian Dominik Speck ◽  
Markus Bierling ◽  
Johannes Bender ◽  
...  

Bipolar membrane|electrode interface water electrolyzers (BPEMWE) were found to outperform a proton exchange membrane (PEM) water electrolyzer reference in a similar membrane electrode assembly (MEA) design based on individual porous...


2018 ◽  
Vol 778 ◽  
pp. 275-282
Author(s):  
Noaman Khan ◽  
Saim Saher ◽  
Xuan Shi ◽  
Muhammad Noman ◽  
Mujahid Wasim Durani ◽  
...  

Highly porous ZIF-67 (Zeolitic imidazole framework) has a conductive crystalline metal organic framework (MOF) structure which was served as a precursor and template for the preparation of nitrogen-doped carbon nanotubes (NCNTs) electrocatalysts. As a first step, the chloroplatinic acid, a platinum (Pt) precursor was infiltrated in ZIF-67 with a precise amount to obtain 0.12 mg.cm-2 Pt loading. Later, the infiltrated structure was calcined at 700°C in Ar:H2 (90:10 vol%) gas mixture. Multi-walled nitrogen-doped carbon nanotubes were grown on the surface of ZIF-67 crystals following thermal activation at 700°C. The resulting PtCo-NCNTs electrocatalysts were deposited on Nafion-212 solid electrolyte membrane by spray technique to study the oxygen reduction reaction (ORR) in the presence of H2/O2 gases in a temperature range of 50-70°C. The present study elucidates the performance of nitrogen-doped carbon nanotubes ORR electrocatalysts derived from ZIF-67 and the effects of membrane electrode assembly (MEA) steaming on the performance of proton exchange membrane fuel cell (PEMFC) employing PtCo-NCNTs as ORR electrocatalysts. We observed that the peak power density at 70°C was 450 mW/cm2 for steamed membrane electrode assembly (MEA) compared to 392 mW/cm2 for an identical MEA without steaming.


Nanoscale ◽  
2017 ◽  
Vol 9 (20) ◽  
pp. 6910-6919 ◽  
Author(s):  
Yachao Zeng ◽  
Xiaoqian Guo ◽  
Zhiqiang Wang ◽  
Jiangtao Geng ◽  
Hongjie Zhang ◽  
...  

Author(s):  
Yusuke Kai ◽  
Yuki Kitayama ◽  
Masaki Omiya ◽  
Tomoaki Uchiyama ◽  
Hideyuki Kumei

The mechanical reliability of the membrane electrode assembly (MEA) in polymer electrolyte fuel cells (PEFCs) is a major concern with respect to fuel cell vehicles. When PEFCs generate power, water is generated. The proton exchange membrane (PEM) swells in wet conditions and shrinks in dry conditions. These cyclic conditions induce mechanical stress in the MEA, and cracks are formed. Failure of the MEA can result in leaking of fuel gases and reduced output power. Therefore, it is necessary to determine the mechanical reliability of the MEA under various mechanical and environmental conditions. The purpose of the present paper is to observe the deformation behavior of the MEA under humidity cycles. We have developed a device in which the constrained condition of the GDL is modeled by carbon bars of 100 to 500 μm in diameter. The carbon bars are placed side by side and are pressed against the MEA. The device was placed in a temperature and humidity controlled chamber, and humidity cycles were applied to the specimen. During the tests, cross sections of the specimen were observed by microscope, and the strain was calculated based on the curvature of the specimen. The temperature in the test chamber was varied from 25 to 80 °C, and the relative humidity was varied from 50 to 100%RH, and the wet condition was also investigated. The results revealed that the MEA deformed significantly by swelling and residual deformation was observed under the dry condition, even for one humidity cycle. The crack formation criteria for one humidity cycle corresponded approximately with those of the static tensile tests. The results of the humidity cycle tests followed Coffin–Manson law, and the number of cycles until crack formation corresponded approximately with the results of the mechanical fatigue tests. These results will be valuable in the critical design of durable PEFCs.


Author(s):  
Faycel Khemili ◽  
Mustapha Najjari ◽  
Sassi Ben Nasrallah

This paper presents one-dimensional transient thermal model for the membrane electrode assembly (MEA) of a proton exchange membrane fuel cell (PEMFC). This model accounts for various heat generating mechanisms, including irreversible heat due to electrochemical reactions, entropic heat, and Joule heating arising from the electrolyte ionic resistance. Numerical results show the effects of many important factors on the transient phenomena in the PEMFC system.


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