PEFC System Reactant Gas Supply Management and Anode Purging Strategy: An Experimental Approach

In this report, a 5 kW PEFC system running on dry hydrogen with an appropriately sized Balance of Plant (BoP) was used to conduct experimental studies and analyses of gas supply subsystems. The improper rating and use of BoP components has been found to increase parasitic loads, which consequently has a direct effect on the polymer electrolyte fuel cell (PEFC) system efficiency. Therefore, the minimisation of parasitic loads while maintaining desired performance is crucial. Nevertheless, little has been found in the literature regarding experimental work on large stacks and BoP, with the majority of papers concentrating on modelling. A particular interest of our study was the anode side of the fuel cell. Additionally the rationale behind the use of hydrogen anode recirculation was scrutinised, and a novel anode purging strategy was developed and implemented. Through experimental modelling, the use of cathode air blower was minimised since it was found to be the biggest contributor to the parasitic loads.

Electrochemical Ammonia: Power to Ammonia Ratio and Balance of Plant Requirements for Two Different Electrolysis Approaches

Electrochemical ammonia generation allows direct, low pressure synthesis of ammonia as an alternative to the established Haber-Bosch process. The increasing need to drive industry with renewable electricity central to decarbonisation and electrochemical ammonia synthesis offers a possible efficient and low emission route for this increasingly important chemical. It also provides a potential route for more distributed and small-scale ammonia synthesis with a reduced production footprint. Electrochemical ammonia synthesis is still early stage but has seen recent acceleration in fundamental understanding. In this work, two different ammonia electrolysis systems are considered. Balance of plant (BOP) requirements are presented and modelled to compare performance and determine trade-offs. The first option (water fed cell) uses direct ammonia synthesis from water and air. The second (hydrogen-fed cell), involves a two-step electrolysis approach firstly producing hydrogen followed by electrochemical ammonia generation. Results indicate that the water fed approach shows the most promise in achieving low energy demand for direct electrochemical ammonia generation. Breaking the reaction into two steps for the hydrogen fed approach introduces a source of inefficiency which is not overcome by reduced BOP energy demands, and will only be an attractive pathway for reactors which promise both high efficiency and increased ammonia formation rate compared to water fed cells. The most optimised scenario investigated here with 90% faradaic efficiency (FE) and 1.5 V cell potential (75% nitrogen utilisation) gives a power to ammonia value of 15 kWh/kg NH3 for a water fed cell. For the best hydrogen fed arrangement, the requirement is 19 kWh/kg NH3. This is achieved with 0.5 V cell potential and 75% utilisation of both hydrogen and nitrogen (90% FE). Modelling demonstrated that balance of plant requirements for electrochemical ammonia are significant. Electrochemical energy inputs dominate energy requirements at low FE, however in cases of high FE the BOP accounts for approximately 50% of the total energy demand, mostly from ammonia separation requirements. In the hydrogen fed cell arrangement, it was also demonstrated that recycle of unconverted hydrogen is essential for efficient operation, even in the case where this increases BOP energy inputs.

Overview of Thermal Hydraulic Optimization and Verification for the EU-DEMO HCPB BOP ICD Variant

When progressing from the International Thermonuclear Experimental Reactor (ITER) to the Demonstration Fusion Reactor (DEMO), a system for transferring plasma heat exhaust to a power conversion system is necessary for the so-called Balance of Plant (BOP). During the preconceptual phase of the EU-DEMO project, different BOP concepts were investigated in order to identify the main requirements and feasible architectures to achieve that goal in the most efficient way. This paper comprises the investigations performed during the DEMO preconceptual design phase (p-CDP) and compares the different variants. The main aspect was focused on the helium-cooled pebble bed (HCPB) breeding blanket (BB) concept. After all assessments were performed, the indirect coupled design (ICD) was chosen as the reference configuration for the DEMO HCPB BOP for further development and optimization. The ICD provides decoupling using a molten salt storage loop, which accumulates thermal power during plasma pulses that are released during dwell periods. The work is supported by simulations using design codes EBSILON and MATLAB/SIMULINK, providing the basis for the next design phase.

Model Development and Transient Analysis of the HCPB BB BOP DEMO Configuration Using the Apros System Code

Extensive modeling and analytical work has been carried out considering the Helium-Cooled Pebble Bed Breeding Blanket (HCPB BB) Balance Of Plant (BOP) configuration of the Demonstration Power Plant (DEMO) using the Apros system code, developed by VTT Technical Research Centre of Finland Ltd. and Fortum. The integral plant model of the HCPB BB plant has been improved with respect to the blanket and steam generator models. Based on HCPB-BL2017 v1 data, reported in 2019, the blanket has been remodeled by separate Apros process components, dedicated to average inboard and outboard segments, where the power deposition scheme of the breeding units took into account the output of high-fidelity neutronic analyses. A new helical coil steam generator model has been developed for primary–secondary system coupling using CAD data provided by EUROfusion partner University of Palermo. Transient analyses have been performed with Apros on the plant configuration that utilizes a molten salt technology-based small Energy Storage System (ESS).

Model Development and Transient Analysis of the WCLL BB BOP DEMO Configuration Using the Apros System Code

Extensive modelling and analytical work has been carried out considering the water-cooled lithium–lead breeding blanket (WCLL BB) balance of plant (BOP) configuration of the demonstration power plant (DEMO) using the Apros system code, developed by VTT Technical Research Centre of Finland Ltd. and Fortum. Contributing to the BOP work package of the EUROfusion Consortium, the integral plant model for dynamic analyses of the WCLL BB configuration has been updated with special attention to primary system components. Following trends of relevant neutronics modelling, a new BB model has been implemented in 2020 with the aim to obtain higher resolution output data and a more realistic thermalhydraulic feedback from the primary system. Once-through steam generator user components have been built based on CAD models conceived by BOP partners. Transient analyses have been performed providing a better picture regarding the behaviour of main components, e.g., the BB and the OTSGs, whilst highlighting possible ways to optimise the control scheme of the plant.

Transcriptome Changes Associated with Boron Applications in Fruits of Watercore-susceptible Pear Cultivar

Watercore is a common physiological disorder in pear and is closely related to excessive accumulation of sorbitol and sucrose. Our previous research found the watercore incidence of ‘Akibae’ (Pyrus pyrifolia cv. Akibae) fruit significantly decreased after boron application (BA). Moreover, foliar spray of boric acid also significantly improved fruit quality. To uncover the mechanisms underlying pear fruit response to BA, a comprehensive transcriptome analysis was performed in this study. Transcriptome results revealed a total of 3146 up-regulated and 1145 down-regulated differently expressed genes (DEGs) between control and treated fruits of ‘Akibae’ pear, respectively. BA significantly induced expression of sorbitol metabolism and sucrose metabolism genes. Besides, BA also increased the expression of starch degradation, fatty acid synthesis, IAA (indole-3-acetic acid) degradation, GA (gibberellin acid) synthesis and inhibit the expression of ethylene synthesis genes. Overall, these findings suggested that BA alleviated ‘Akibae’ watercore occurrence and improve fruit quality by regulating the decrease of sorbitol and sucrose, increased of fatty acid and a balance of plant hormone. Our results provided further information for understanding the molecular mechanism of the effect of boron application on pear fruit.

ZmACY-1 Antagonistically Regulates Growth and Stress Responses in Nicotiana benthamiana

Aminoacylase-1 is a zinc-binding enzyme that is important in urea cycling, ammonia scavenging, and oxidative stress responses in animals. Aminoacylase-1 (ACY-1) has been reported to play a role in resistance to pathogen infection in the model plant Nicotiana benthamiana. However, little is known about its function in plant growth and abiotic stress responses. In this study, we cloned and analyzed expression patterns of ZmACY-1 in Zea mays under different conditions. We also functionally characterized ZmACY-1 in N. benthamiana. We found that ZmACY-1 is expressed specifically in mature shoots compared with other tissues. ZmACY-1 is repressed by salt, drought, jasmonic acid, and salicylic acid, but is induced by abscisic acid and ethylene, indicating a potential role in stress responses and plant growth. The overexpression of ZmACY-1 in N. benthamiana promoted growth rate by promoting growth-related genes, such as NbEXPA1 and NbEIN2. At the same time, the overexpression of ZmACY-1 in N. benthamiana reduced tolerance to drought and salt stress. With drought and salt stress, the activity of protective enzymes, such as peroxidase (POD), superoxide dismutase (SOD), and catalase (CAT) from micrococcus lysodeikticus was lower; while the content of malondialdehyde (MDA) and relative electrolytic leakage was higher in ZmACY-1 overexpression lines than that in wild-type lines. The results indicate that ZmACY-1 plays an important role in the balance of plant growth and defense and can be used to assist plant breeding under abiotic stress conditions.