Development and Application of an Eight-Step Global Mechanism for CFD and CRN Simulations of Lean-Premixed Combustors

2007 ◽  
Author(s):  
Igor V. Novosselov ◽  
Philip C. Malte
Keyword(s):  
Chemical Reactor ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Lean Premixed Combustion ◽  
Chemical Reactor Network ◽  
Elevated Pressures ◽  
Nitric Oxide Formation ◽  
No Formation ◽  
Lean Premixed ◽  
Reactor Network

In this paper, the development of an eight-step global chemical kinetic mechanism for methane oxidation with nitric oxide formation in lean-premixed combustion at elevated pressures is described and applied. In particular, the mechanism has been developed for use in computational fluid dynamics (CFD) and chemical reactor network (CRN) simulations of combustion in lean-premixed gas turbine engines. Special attention is focused on the ability of the mechanism to predict NOx and CO exhaust emissions. Applications of the eight-step mechanism are reported in the paper, all for high-pressure, lean-premixed, methane-air (or natural gas-air) combustion. The eight steps of the mechanism are as follows: 1. Oxidation of the methane fuel to CO and H2O. 2. Oxidation of the CO to CO2. 3. Dissociation of the CO2 to CO. 4. Flame NO formation by the Zeldovich and nitrous oxide mechanisms. 5. Flame NO formation by the prompt and NNH mechanisms. 6. Post-flame NO formation by equilibrium H-atom attack on equilibrium N2O. 7. Post-flame NO formation by equilibrium O-atom attack on equilibrium N2O. 8. Post-flame Zeldovich NO formation by equilibrium O-atom attack on N2.

Development and Application of an Eight-Step Global Mechanism for CFD and CRN Simulations of Lean-Premixed Combustors

2008 ◽  
Vol 130 (2) ◽  
Author(s):  
Igor V. Novosselov ◽  
Philip C. Malte
Keyword(s):  
Chemical Reactor ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Lean Premixed Combustion ◽  
Chemical Reactor Network ◽  
Elevated Pressures ◽  
No Formation ◽  
Lean Premixed ◽  
Network Simulations ◽  
Reactor Network

In this paper, the development of an eight-step global chemical kinetic mechanism for methane oxidation with nitric oxide formation in lean-premixed combustion at elevated pressures is described and applied. In particular, the mechanism has been developed for use in computational fluid dynamics and chemical reactor network simulations of combustion in lean-premixed gas turbine engines. Special attention is focused on the ability of the mechanism to predict NOx and CO exhaust emissions. Applications of the eight-step mechanism are reported in the paper, all for high-pressure, lean-premixed, methane-air (or natural gas-air) combustion. The eight steps of the mechanism are as follows: (1) oxidation of the methane fuel to CO and H2O, (2) oxidation of the CO to CO2, (3) dissociation of the CO2 to CO, (4) flame-NO formation by the Zeldovich and nitrous oxide mechanisms, (5) flame-NO formation by the prompt and NNH mechanisms, (6) postflame-NO formation by equilibrium H-atom attack on equilibrium N2O, (7) postflame-NO formation by equilibrium O-atom attack on equilibrium N2O, and (8) postflame Zeldovich NO formation by equilibrium O-atom attack on N2.

Chemical Reactor Network Application to Emissions Prediction for Industial DLE Gas Turbine

2006 ◽  
Author(s):  
I. V. Novosselov ◽  
P. C. Malte ◽  
S. Yuan ◽  
R. Srinivasan ◽  
J. C. Y. Lee
Keyword(s):  
Gas Turbine ◽  
Chemical Reactor ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Operating Conditions ◽  
Reacting Flow ◽  
Ongoing Research ◽  
Chemical Reactor Network ◽  
Reaction Zones ◽  
Reactor Network

A chemical reactor network (CRN) is developed and applied to a dry low emissions (DLE) industrial gas turbine combustor with the purpose of predicting exhaust emissions. The development of the CRN model is guided by reacting flow computational fluid dynamics (CFD) using the University of Washington (UW) eight-step global mechanism. The network consists of 31 chemical reactor elements representing the different flow and reaction zones of the combustor. The CRN is exercised for full load operating conditions with variable pilot flows ranging from 35% to 200% of the neutral pilot. The NOpilot. The NOx and the CO emissions are predicted using the full GRI 3.0 chemical kinetic mechanism in the CRN. The CRN results closely match the actual engine test rig emissions output. Additional work is ongoing and the results from this ongoing research will be presented in future publications.

Prediction of NOx and CO Emissions from an Industrial Lean-Premixed Gas Turbine Combustor Using a Chemical Reactor Network Model

2013 ◽  
Vol 27 (3) ◽  
pp. 1643-1651 ◽  
Author(s):  
Jungkyu Park ◽  
Truc Huu Nguyen ◽  
Daero Joung ◽  
Kang Yul Huh ◽  
Min Chul Lee
Keyword(s):  
Gas Turbine ◽  
Network Model ◽  
Chemical Reactor ◽  
Gas Turbine Combustor ◽  
Chemical Reactor Network ◽  
Lean Premixed ◽  
Reactor Network

NO x Formation in High-Pressure Jet-Stirred Reactors With Significance to Lean-Premixed Combustion Turbines

2002 ◽  
Vol 124 (4) ◽  
pp. 776-783 ◽  
Author(s):  
T. Rutar ◽  
P. C. Malte
Keyword(s):  
High Pressure ◽  
Nitrous Oxide ◽  
Chemical Reactor ◽  
Kinetic Mechanism ◽  
Chemical Kinetic ◽  
Sampling Point ◽  
Flame Zone ◽  
Formation Pathway ◽  
Lean Premixed ◽  
Stirred Reactors

Measurements of NOx and CO in methane-fired, lean-premixed, high-pressure jet-stirred reactors (HP-JSRs), independently obtained by two researchers, are well predicted assuming simple chemical reactor models and the GRI 3.0 chemical kinetic mechanism. The single-jet HP-JSR is well modeled for NOx and CO assuming a single PSR for Damko¨hler number below 0.15. Under these conditions, the estimates of flame thickness indicate the flame zone, that is, the region of rapid oxidation and large concentrations of free radicals, fully fills the HP-JSR. For Damko¨hler number above 0.15, that is, for longer residence times, the NOx and CO are well modeled assuming two perfectly stirred reactors (PSRs) in series, representing a small flame zone followed by a large post-flame zone. The multijet HP-JSR is well modeled assuming a large PSR (over 88% of the reactor volume) followed by a short PFR, which accounts for the exit region of the HP-JSR and the short section of exhaust prior to the sampling point. The Damko¨hler number is estimated between 0.01 and 0.03. Our modeling shows the NOx formation pathway contributions. Although all pathways, including Zeldovich (under the influence of super-equilibrium O-atom), nitrous oxide, Fenimore prompt, and NNH, contribute to the total NOx predicted, of special note are the following findings: (1) NOx formed by the nitrous oxide pathway is significant throughout the conditions studied; and (2) NOx formed by the Fenimore prompt pathway is significant when the fuel-air equivalence ratio is greater than about 0.7 (as might occur in a piloted lean-premixed combustor) or when the residence time of the flame zone is very short. The latter effect is a consequence of the short lifetime of the CH radical in flames.

Sign in / Sign up

Export Citation Format

Share Document