Investigation of Oxy-Fuel Combustion through Reactor Network and Residence Time Data

Oxy-fuel combustion is a promising strategy to minimize the environmental impact of combustion-based energy conversion. Simple and flexible tools are required to facilitate the successful integration of such strategies at the industrial level. This study couples measured residence time distribution with chemical reactor network analysis in a close-to-reality combustor. This provides detailed knowledge about the various mixing and reactive characteristics arising from the use of the two different oxidizing streams.

Exploring Use of Hydrogen for Extending Operability of a Full-Scale Annular Combustor

In anticipation of increased use of hydrogen as a means of decarbonizing future power generation used widely in combined heat and power plants, studies are underway to understand how hydrogen impacts operability and emissions from existing low emission gas turbines. In the current study, a full-scale annular combustor is used to study how added hydrogen to methane (as a proxy for natural gas) impacts lean blow-off limits. Of particular interest is understanding if hydrogen can be used strategically to extend low emissions operation at lower load. This would facilitate use of gas turbines to offset intermittent renewable power which is becoming increasing integrated into microgrid environments where combined heat and power system are prevalent. A combined experimental and numerical approach is taken. Tests were carried out at Southwest Research Institute using a full-scale annular combustor test rig at elevated temperatures and atmospheric pressure. The individual fuel injectors used were piloted injectors based on natural gas injectors used in practice. Various blends of hydrogen and methane were tested for different scaled load conditions and different pilot to main fuel splits. Besides identifying the overall equivalence ratio at blow-off, measurements also included temperature uniformity at the exit plane and imaging of the reaction. To complement and extend the study a chemical reactor network approach was also applied. The reactor network was initially validated on a prior study involving use of a piloted model combustor. The reactor network was applied to the current configuration and further tuned to align with the measured data. The agreement between the reactor network blow-off and measured blow-off was reasonable. The validated reactor network was then used in combination with a statistically designed simulation matrix to derive a design tool. The tool is then used to estimate other performance features including CO emissions near LBO and the impacts of ambient humidity and the presence of higher hydrocarbons typically found in natural gas. The design tool quantifies the extent to which hydrogen content and pilot percentage can extended part load operability for the full annular combustor system.

Optimal Fixed Bed Reactor Network Configuration for the Efficient Recycling of CO2 into Methanol

An optimal design strategy of a network of fixed bed reactors for Methanol Production (MP) is proposed in this study. Both methanol production and profit spanning a production period of eight years have been set as objective functions to find the optimal production network. The conservation of mass and energy laws on a heterogeneous model of a single industrial methanol reactor was first developed. The model was solved numerically and was validated with industrial plant data. Different reactor network arrangements were then simulated in order to find an optimal superstructure. It was found that a structure of four reactors (two in series in parallel with another two in series) provide maximum production rate. The application of the more realistic objective function of profit showed that a configuration of two parallel reactors is the best configuration. This optimal structure produces 92 tons/day more methanol than a single reactor.

Optimal Fixed Bed Reactor Network Configuration for the Efficient Recycling of CO2 into Methanol

An optimal design strategy of a network of fixed bed reactors for Methanol Production (MP) is proposed in this study. Both methanol production and profit spanning a production period of eight years have been set as objective functions to find the optimal production network. The conservation of mass and energy laws on a heterogeneous model of a single industrial methanol reactor was first developed. The model was solved numerically and was validated with industrial plant data. Different reactor network arrangements were then simulated in order to find an optimal superstructure. It was found that a structure of four reactors (two in series in parallel with another two in series) provide maximum production rate. The application of the more realistic objective function of profit showed that a configuration of two parallel reactors is the best configuration. This optimal structure produces 92 tons/day more methanol than a single reactor.

Research on the flame structure characteristics and NOx pathways of low swirl combustion

Low swirl combustion (LSC) technology has the advantage of ultralow NOx emissions, which is of great significance to the development of low-emission gas turbine engines in the future. To investigate the flow field and flame structure characteristics of LSC, a test rig of low swirl burner was designed and developed. Particle image velocimetry measurement results show that the location and size of the recirculation zone are different, and the flow field shows typical “W”- and “U”-shaped distributions under various swirling flow conditions. The self-luminous results of LSC show that there are three flame modes including attached flame, “W”-shaped flame, and “U”-shaped flame. To deeply understand NOx generation pathways, a chemical reactor network model was developed based on experiments and computational fluid dynamics simulations, and the effects of premixed gas components on NOx pathways were calculated by using Chemkin software. It was verified that the NOx production of the CH4 mixture mixed with H2, N2, and CO2 was mainly formed by the thermal NO pathway in the recirculation zone. The increase of H2 promotes the generation of NNH-type NOx in the main flame zone and inhibits prompt NOx. The addition of N2 and CO2 greatly promotes the generation of prompt NOx and at the same time inhibits NNH-type NOx. In addition, there is little prompt NOx formation in the post-flame zone.