Impact Behavior of Liquid Crystalline Polymers
Liquid crystalline polymers have the advantage of achieving desirable mechanical properties at a competitive cost. They are composed of molecular chains that are highly oriented and tightly packed at temperatures above and below its melting point. This high degree of orientation has the following advantages: ease of processing, high mechanical strength at extreme temperatures, and resistance to mostly all chemicals, weathering, radiation, and burning. On the other hand, this high degree of orientation causes liquid crystalline polymers to have low impact strength as well as an uneven amount of shrinkage prior to molding. The objective of this study is to determine the effects of injection-molding parameters on the impact behavior of liquid crystalline polymers, in an attempt to improve and understand the processing of the material. The conditions to be tested are as follows: fill speed, initial mold temperature, and packing pressure. The impact tester used for this research was an Instron Dynatup tester. Based on the data, it is apparent that fill speed is the greatest determining factor for optimizing the impact energy of the injection-molded liquid crystalline polymers followed by high packing pressure. In addition, even though the nature of the impact energy curves for LCPs and materials such as Delrin are similar, the impact load curves as a function of time are significantly different. This can be attributed to the layered structure of LCP samples.