In-Situ Observations of Intergranular Stress Corrosion Cracking

Author(s):  
Jonathan A. Duff ◽  
Thomas J. Marrow

The development and validation of predictive models for intergranular stress corrosion cracking requires knowledge of short crack growth kinetics in response to mechanical driving forces. A new experimental method for in-situ observation of the early stages of crack growth during stress corrosion cracking, via full field Digital Image Correlation, is described and data for crack growth development are presented. Intergranular stress corrosion cracks were nucleated in sensitised 304 stainless steel under static uniaxial flexural deflection, within a potassium tetrathionate environment. High resolution optical images of a 2mm by 2mm area are recorded through the test solution during the experiment. The raw images show no observable cracking. However, the high sensitivity of digital image correlation allows small crack opening displacements to be detected. The derived strain map of the sample surface thereby enables imaging of the cracks. Surface cracks with lengths exceeding approximately 30μm can be observed. Post processing of the strain maps is then used to track the development of the cracks.

CORROSION ◽  
10.5006/2853 ◽  
2018 ◽  
Vol 74 (10) ◽  
pp. 1117-1131 ◽  
Author(s):  
P.J. Steiner ◽  
J.T. Burns

The effect of atmospheric environments on the intergranular stress corrosion cracking (IG-SCC) behavior of AA5083-H131 and AA5456-H116 was investigated using fracture mechanics-based testing, high-fidelity monitoring of crack growth kinetics, and electrochemical potential measurements. The IG-SCC susceptibility was found to decrease in atmospheric environments as compared to full immersion at −0.8 VSCE. Critically, the decrease in IG-SCC susceptibility was most prevalent for higher levels of sensitization and the more susceptible AA5083-H131 alloy. These results are analyzed in the context of a coupled anodic dissolution and H-embrittlement mechanism, wherein the reduction in IG-SCC susceptibility in the atmospheric environments results from cathodic limitation of the governing IG-SCC mechanism, leading to a decrease in the dissolution at the crack tip, a less aggressive crack chemistry development, and thus lower levels of H production. A close correlation between the open circuit potential of the bulk surface and the crack growth kinetics was observed for environments without a set potential, and correlates well with known potential-dependent IG-SCC observations.


CORROSION ◽  
1986 ◽  
Vol 42 (2) ◽  
pp. 99-105 ◽  
Author(s):  
Y. S. Garud ◽  
A. R. McIlree

Abstract A logical approach to quantitative modeling of intergranular stress corrosion cracking (IGSCC) is presented. The approach is based on the supposition (supported partly by experimental and field observations, and by a related plausible underlying mechanism) that strain rate is a key variable. The approach is illustrated for the specific case of NiCrFe Alloy 600 in high-purity water. Model parameters are determined based on the constant stress IGSCC data (between 290 and 365 C) assuming a power law relation between the damage and the nominal strain rate. The model may be interpreted in terms of a film rupture mechanism of the corrosion process. The related mechanistic considerations are examined for the specific case. Resulting calculations and stress as well as temperature dependence are shown to be in good agreement with the data. More data are needed for further verification under specific conditions of interest.


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